Literature DB >> 30265433

The H2 S Dimer is Hydrogen-Bonded: Direct Confirmation from Microwave Spectroscopy.

Arijit Das1, Pankaj K Mandal2, Frank J Lovas3, Chris Medcraft4, Nicholas R Walker5, Elangannan Arunan1.   

Abstract

Ice and solid H2 S look as different as pears and oranges, leading Pauling to conclude that H2 O has hydrogen bonds and H2 S has van der Waals interactions. Now it is shown that the H2 S dimer, like the H2 O dimer, is indeed hydrogen-bonded.
© 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  hydrogen bonding; hydrogen sulfide; van der Waals interactions; water; weakly bound complexes

Year:  2018        PMID: 30265433     DOI: 10.1002/anie.201808162

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN: 1433-7851            Impact factor:   15.336


  4 in total

1.  Hydrogen Bonding in the Dimer and Monohydrate of 2-Adamantanol: A Test Case for Dispersion-Corrected Density Functional Methods.

Authors:  Marcos Juanes; Rizalina Tama Saragi; Cristóbal Pérez; Luca Evangelisti; Lourdes Enríquez; Martín Jaraíz; Alberto Lesarri
Journal:  Molecules       Date:  2022-04-17       Impact factor: 4.927

2.  Energetic electron irradiations of amorphous and crystalline sulphur-bearing astrochemical ices.

Authors:  Duncan V Mifsud; Péter Herczku; Richárd Rácz; K K Rahul; Sándor T S Kovács; Zoltán Juhász; Béla Sulik; Sándor Biri; Robert W McCullough; Zuzana Kaňuchová; Sergio Ioppolo; Perry A Hailey; Nigel J Mason
Journal:  Front Chem       Date:  2022-09-26       Impact factor: 5.545

3.  Biocompatible metal-organic frameworks for the storage and therapeutic delivery of hydrogen sulfide.

Authors:  Faith E Chen; Ruth M Mandel; Joshua J Woods; Jung-Hoon Lee; Jaehwan Kim; Jesse H Hsu; José J Fuentes-Rivera; Justin J Wilson; Phillip J Milner
Journal:  Chem Sci       Date:  2021-04-30       Impact factor: 9.969

4.  Switching Hydrogen Bonding to π-Stacking: The Thiophenol Dimer and Trimer.

Authors:  Rizalina Tama Saragi; Marcos Juanes; Cristóbal Pérez; Pablo Pinacho; Denis S Tikhonov; Walther Caminati; Melanie Schnell; Alberto Lesarri
Journal:  J Phys Chem Lett       Date:  2021-01-28       Impact factor: 6.475

  4 in total

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