| Literature DB >> 30209448 |
M Talavera1, A Peña-Gallego, J L Alonso-Gómez, S Bolaño.
Abstract
Synthesis of stable irida-binaphthyl and -phenanthryl complexes, the first examples of metallaaromatic biaryl atropisomers, has been achieved. The combination of experimental and theoretical studies revealed that the nature of these systems is comparable to that of well-known 1,1'-binaphthalene both in terms of aromaticity and atropisomerism.Entities:
Year: 2018 PMID： 30209448 DOI： 10.1039/c8cc06443a
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222