Au-TiO2-Loaded Cubic g-C3N4 Nanohybrids for Photocatalytic and Volatile Organic Amine Sensing Applications.

A green and efficient approach for efficient nanohybrid photocatalysts in extending the light response to the visible spectrum is a hot research topic in sustainable energy technologies. In this work, novel Au-TiO2@m-CN nanocomposite was synthesized using hard template of cubic ordered mesoporous KIT-6 via the nanocasting process. The as-prepared Au-TiO2@m-CN nanohybrids exhibit enhanced photocatalytic activities with improved stability and reusability using methyl orange dye. The enhanced photocatalytic performance is a result of the conjugated effect of catalytic active Au and TiO2 nanoparticles supported on highly efficient visible light sensitizer, graphitic carbon nitride (m-CN or g-C3N4), and ordered mesoporous morphology. Besides, the sensing performance of Au-TiO2@m-CN nanohybrids was also tested for the detection of amine gases, wherein a significant response was reported for triethylamine at low operating temperatures. This study reveals a simple and scalable methodology to design and develop next generation of layered mesoporous materials for multifunctional applications.