Warning: Undefined array key "mm" in /www/wwwroot/www.ai-bt.com/si.php on line 10 Deprecated: trim(): Passing null to parameter #1 ($string) of type string is deprecated in /www/wwwroot/www.ai-bt.com/si.php on line 10 Methane Storage in Paddlewheel-Based Porous Coordination Cages.

Literature DB >> 30122041

Methane Storage in Paddlewheel-Based Porous Coordination Cages.

Casey A Rowland, Gregory R Lorzing, Eric J Gosselin, Benjamin A Trump¹, Glenn P A Yap, Craig M Brown¹, Eric D Bloch.

Abstract

Although gas adsorption properties of extended three-dimensional metal-organic materials have been widely studied, they remain relatively unexplored in porous molecular systems. This is particularly the case for porous coordination cages for which surface areas are typically not reported. Herein, we report the synthesis, characterization, activation, and gas adsorption properties of a family of carbazole-based cages. The chromium analog displays a coordination cage record BET (Brunauer-Emmett-Teller) surface area of 1235 m2/g. With precise synthesis and activation procedures, two previously reported cages similarly display high surface areas. The materials exhibit high methane adsorption capacities at 65 bar with the chromium(II) cage displaying CH4 capacities of 194 cm3/g and 148 cm3/cm3. This high uptake is a result of optimal pore design, which was confirmed via powder neutron diffraction experiments.

Entities: CellLine Chemical Disease Species

Mesh：

Substances：

Year: 2018 PMID： 30122041 PMCID： PMC6207189 DOI： 10.1021/jacs.8b05780

Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419

24 in total

1. Porous organic cages.

Authors: Tomokazu Tozawa; James T A Jones; Shashikala I Swamy; Shan Jiang; Dave J Adams; Stephen Shakespeare; Rob Clowes; Darren Bradshaw; Tom Hasell; Samantha Y Chong; Chiu Tang; Stephen Thompson; Julia Parker; Abbie Trewin; John Bacsa; Alexandra M Z Slawin; Alexander Steiner; Andrew I Cooper
Journal: Nat Mater Date: 2009-10-25 Impact factor: 43.841

2. Fuel prices, emission standards, and generation costs for coal vs natural gas power plants.

Authors: Lincoln F Pratson; Drew Haerer; Dalia Patiño-Echeverri
Journal: Environ Sci Technol Date: 2013-04-04 Impact factor: 9.028

3. Poly(isophthalic acid)(ethylene oxide) as a Macromolecular Modulator for Metal-Organic Polyhedra.

Authors: Teng-Hao Chen; Le Wang; Jonathan V Trueblood; Vicki H Grassian; Seth M Cohen
Journal: J Am Chem Soc Date: 2016-07-22 Impact factor: 15.419

4. Separation of rare gases and chiral molecules by selective binding in porous organic cages.

Authors: Linjiang Chen; Paul S Reiss; Samantha Y Chong; Daniel Holden; Kim E Jelfs; Tom Hasell; Marc A Little; Adam Kewley; Michael E Briggs; Andrew Stephenson; K Mark Thomas; Jayne A Armstrong; Jon Bell; Jose Busto; Raymond Noel; Jian Liu; Denis M Strachan; Praveen K Thallapally; Andrew I Cooper
Journal: Nat Mater Date: 2014-07-20 Impact factor: 43.841

5. A sol-gel monolithic metal-organic framework with enhanced methane uptake.

Authors: Tian Tian; Zhixin Zeng; Diana Vulpe; Mirian E Casco; Giorgio Divitini; Paul A Midgley; Joaquin Silvestre-Albero; Jin-Chong Tan; Peyman Z Moghadam; David Fairen-Jimenez
Journal: Nat Mater Date: 2017-12-11 Impact factor: 43.841

6. Design, synthesis, structure, and gas (N2, Ar, CO2, CH4, and H2) sorption properties of porous metal-organic tetrahedral and heterocuboidal polyhedra.

Authors: Andrea C Sudik; Andrew R Millward; Nathan W Ockwig; Adrien P Côté; Jaheon Kim; Omar M Yaghi
Journal: J Am Chem Soc Date: 2005-05-18 Impact factor: 15.419

7. Chromium(II) Metal-Organic Polyhedra as Highly Porous Materials.

Authors: Jinhee Park; Zachary Perry; Ying-Pin Chen; Jaeyeon Bae; Hong-Cai Zhou
Journal: ACS Appl Mater Interfaces Date: 2017-08-10 Impact factor: 9.229

8. Storage of hydrogen, methane, and carbon dioxide in highly porous covalent organic frameworks for clean energy applications.

Authors: Hiroyasu Furukawa; Omar M Yaghi
Journal: J Am Chem Soc Date: 2009-07-01 Impact factor: 15.419

9. Methane storage in flexible metal-organic frameworks with intrinsic thermal management.

Authors: Jarad A Mason; Julia Oktawiec; Mercedes K Taylor; Matthew R Hudson; Julien Rodriguez; Jonathan E Bachman; Miguel I Gonzalez; Antonio Cervellino; Antonietta Guagliardi; Craig M Brown; Philip L Llewellyn; Norberto Masciocchi; Jeffrey R Long
Journal: Nature Date: 2015-10-26 Impact factor: 49.962

Methane Storage in Paddlewheel-Based Porous Coordination Cages.

1. Porous organic cages.

2. Fuel prices, emission standards, and generation costs for coal vs natural gas power plants.

3. Poly(isophthalic acid)(ethylene oxide) as a Macromolecular Modulator for Metal-Organic Polyhedra.

4. Separation of rare gases and chiral molecules by selective binding in porous organic cages.

5. A sol-gel monolithic metal-organic framework with enhanced methane uptake.

6. Design, synthesis, structure, and gas (N2, Ar, CO2, CH4, and H2) sorption properties of porous metal-organic tetrahedral and heterocuboidal polyhedra.

7. Chromium(II) Metal-Organic Polyhedra as Highly Porous Materials.

8. Storage of hydrogen, methane, and carbon dioxide in highly porous covalent organic frameworks for clean energy applications.

9. Methane storage in flexible metal-organic frameworks with intrinsic thermal management.

10. High methane storage capacity in aluminum metal-organic frameworks.

1. Understanding Gas Storage in Cuboctahedral Porous Coordination Cages.

2. A Coordinative Solubilizer Method to Fabricate Soft Porous Materials from Insoluble Metal-Organic Polyhedra.

3. A new iron-based metal-organic framework with enhancing catalysis activity for benzene hydroxylation.

4. Continuum Modeling with Functional Lennard-Jones Parameters for Methane Storage inside Various Carbon Nanostructures.

5. Permanent Porosity in Hydroxamate Titanium-Organic Polyhedra.