Literature DB >> 29975378

Directed ortho C-H borylation catalyzed using Cp*Rh(iii)-NHC complexes.

Jompol Thongpaen1, Thibault E Schmid, Loic Toupet, Vincent Dorcet, Marc Mauduit, Olivier Baslé.   

Abstract

Cp*Rh(NHC) complexes with bulky chiral bidentate NHC-carboxylate ligands were efficiently synthesized and fully characterized including solid-state structures. These unprecedented rhodium(iii) complexes demonstrated high selectivity in pyridine-directed ortho-C-H borylation of arenes under mild conditions.

Entities:  

Year:  2018        PMID: 29975378     DOI: 10.1039/c8cc03144d

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  6 in total

Review 1.  Inorganometallics (Transition Metal-Metalloid Complexes) and Catalysis.

Authors:  Bogdan Marciniec; Cezary Pietraszuk; Piotr Pawluć; Hieronim Maciejewski
Journal:  Chem Rev       Date:  2021-12-30       Impact factor: 60.622

2.  Antimicrobial Properties of Amino-Acid-Derived N-Heterocyclic Carbene Silver Complexes.

Authors:  Adrián Sánchez; Carlos J Carrasco; Francisco Montilla; Eleuterio Álvarez; Agustín Galindo; María Pérez-Aranda; Eloísa Pajuelo; Ana Alcudia
Journal:  Pharmaceutics       Date:  2022-03-30       Impact factor: 6.525

Review 3.  N-Heterocyclic Carbene Complexes in C-H Activation Reactions.

Authors:  Qun Zhao; Guangrong Meng; Steven P Nolan; Michal Szostak
Journal:  Chem Rev       Date:  2020-01-22       Impact factor: 60.622

4.  Computational understanding of catalyst-controlled borylation of fluoroarenes: directed vs. undirected pathway.

Authors:  Yu-Hua Liu; Zhong-Jie Jiang
Journal:  RSC Adv       Date:  2020-05-21       Impact factor: 4.036

Review 5.  Recent Advances in Catalysis Involving Bidentate N-Heterocyclic Carbene Ligands.

Authors:  Abdollah Neshat; Piero Mastrorilli; Ali Mousavizadeh Mobarakeh
Journal:  Molecules       Date:  2021-12-24       Impact factor: 4.411

6.  Rhodium Indenyl NHC and Fluorenyl-Tethered NHC Half-Sandwich Complexes: Synthesis, Structures and Applications in the Catalytic C-H Borylation of Arenes and Alkanes.

Authors:  Kieren J Evans; Paul A Morton; Christian Luz; Callum Miller; Olivia Raine; Jason M Lynam; Stephen M Mansell
Journal:  Chemistry       Date:  2021-11-18       Impact factor: 5.020

  6 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.