Literature DB >> 29860826

Continuous Endoperoxidation of Conjugated Dienes and Subsequent Rearrangements Leading to C-H Oxidized Synthons.

Juliana M de Souza1, Timothy J Brocksom1,2, D Tyler McQuade3, Kleber T de Oliveira1.   

Abstract

We have investigated the continuous flow photooxidation of several conjugated dienes and subsequent rearrangement using a practical and safe continuous-flow homemade engineered setup. End-to-end approaches involving endoperoxidation, Kornblum-DeLaMare rearrangement, and additional rearrangements are comprehensively detailed with optimization, scope, and scale-up to obtain useful hydroxyenones, furans, and 1,4-dicarbonyl building blocks.

Entities:  

Year:  2018        PMID： 29860826     DOI： 10.1021/acs.joc.8b01307

Source DB:  PubMed          Journal:  J Org Chem        ISSN： 0022-3263            Impact factor:   4.354


  7 in total

Review 1.  Technological Innovations in Photochemistry for Organic Synthesis: Flow Chemistry, High-Throughput Experimentation, Scale-up, and Photoelectrochemistry.

Authors:  Laura Buglioni; Fabian Raymenants; Aidan Slattery; Stefan D A Zondag; Timothy Noël
Journal:  Chem Rev       Date:  2021-08-10       Impact factor: 60.622

2.  Scaled up and telescoped synthesis of propofol under continuous-flow conditions.

Authors:  Guilherme M Martins; Maria F A Magalhães; Timothy J Brocksom; Vanderlei S Bagnato; Kleber T de Oliveira
Journal:  J Flow Chem       Date:  2022-07-19       Impact factor: 3.264

3.  Nanocrystals perovskites photocatalyzed singlet oxygen generation for light-driven organic reactions.

Authors:  Marco Corti; Rossella Chiara; Lidia Romani; Barbara Mannucci; Lorenzo Malavasi; Paolo Quadrelli
Journal:  Photochem Photobiol Sci       Date:  2021-10-06       Impact factor: 4.328

4.  Discovery of four modified classes of triterpenoids delineated a metabolic cascade: compound characterization and biomimetic synthesis.

Authors:  Bin Zhou; Xin-Hua Gao; Min-Min Zhang; Cheng-Yu Zheng; Hong-Chun Liu; Jian-Min Yue
Journal:  Chem Sci       Date:  2021-06-18       Impact factor: 9.825

Review 5.  Recent Visible Light and Metal Free Strategies in [2+2] and [4+2] Photocycloadditions.

Authors:  Marina Sicignano; Ricardo I Rodríguez; José Alemán
Journal:  European J Org Chem       Date:  2021-06-10

Review 6.  Recent applications of porphyrins as photocatalysts in organic synthesis: batch and continuous flow approaches.

Authors:  Rodrigo Costa E Silva; Luely Oliveira da Silva; Aloisio de Andrade Bartolomeu; Timothy John Brocksom; Kleber Thiago de Oliveira
Journal:  Beilstein J Org Chem       Date:  2020-05-06       Impact factor: 2.883

7.  A Cleavable C2-Symmetric trans-Cyclooctene Enables Fast and Complete Bioorthogonal Disassembly of Molecular Probes.

Authors:  Martin Wilkovitsch; Maximilian Haider; Barbara Sohr; Barbara Herrmann; Jenna Klubnick; Ralph Weissleder; Jonathan C T Carlson; Hannes Mikula
Journal:  J Am Chem Soc       Date:  2020-10-29       Impact factor: 15.419
  7 in total

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