Literature DB >> 29782692

The Influence of Chemical Modification on Linker Rotational Dynamics in Metal-Organic Frameworks.

Joshua T Damron1, Jialiu Ma1, Ricardo Kurz2, Kay Saalwächter2, Adam J Matzger1,3, Ayyalusamy Ramamoorthy1,4.   

Abstract

The robust synthetic flexibility of metal-organic frameworks (MOFs) offers a promising class of tailorable materials, for which the ability to tune specific physicochemical properties is highly desired. This is achievable only through a thorough description of the consequences for chemical manipulations both in structure and dynamics. Magic angle spinning solid-state NMR spectroscopy offers many modalities in this pursuit, particularly for dynamic studies. Herein, we employ a separated-local-field NMR approach to show how specific intraframework chemical modifications to MOF UiO-66 heavily modulate the dynamic evolution of the organic ring moiety over several orders of magnitude.
© 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  NMR spectroscopy; density functional theory; dynamics; metal-organic frameworks; microporous materials

Mesh:

Substances:

Year:  2018        PMID: 29782692      PMCID: PMC6289050          DOI: 10.1002/anie.201805004

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN: 1433-7851            Impact factor:   15.336


  23 in total

1.  A switchable molecular rotator: neutron spectroscopy study on a polymeric spin-crossover compound.

Authors:  J Alberto Rodríguez-Velamazán; Miguel A González; José A Real; Miguel Castro; M Carmen Muñoz; Ana B Gaspar; Ryo Ohtani; Masaaki Ohba; Ko Yoneda; Yuh Hijikata; Nobuhiro Yanai; Motohiro Mizuno; Hideo Ando; Susumu Kitagawa
Journal:  J Am Chem Soc       Date:  2012-03-12       Impact factor: 15.419

2.  How linker's modification controls swelling properties of highly flexible iron(III) dicarboxylates MIL-88.

Authors:  Patricia Horcajada; Fabrice Salles; Stefan Wuttke; Thomas Devic; Daniela Heurtaux; Guillaume Maurin; Alexandre Vimont; Marco Daturi; Olivier David; Emmanuel Magnier; Norbert Stock; Yaroslav Filinchuk; Dmitry Popov; Christian Riekel; Gérard Férey; Christian Serre
Journal:  J Am Chem Soc       Date:  2011-10-14       Impact factor: 15.419

3.  Flexible Metal-Organic Frameworks: Recent Advances and Potential Applications.

Authors:  Ze Chang; Dong-Hui Yang; Jian Xu; Tong-Liang Hu; Xian-He Bu
Journal:  Adv Mater       Date:  2015-08-13       Impact factor: 30.849

4.  Dynamic motion of building blocks in porous coordination polymers.

Authors:  Satoshi Horike; Ryotaro Matsuda; Daisuke Tanaka; Seijiro Matsubara; Motohiro Mizuno; Kazunaka Endo; Susumu Kitagawa
Journal:  Angew Chem Int Ed Engl       Date:  2006-11-06       Impact factor: 15.336

5.  Amphidynamic character of crystalline MOF-5: rotational dynamics of terephthalate phenylenes in a free-volume, sterically unhindered environment.

Authors:  Stephanie L Gould; David Tranchemontagne; Omar M Yaghi; Miguel A Garcia-Garibay
Journal:  J Am Chem Soc       Date:  2008-02-21       Impact factor: 15.419

6.  Intermediate motions as studied by solid-state separated local field NMR experiments.

Authors:  Eduardo Ribeiro deAzevedo; Kay Saalwachter; Ovidiu Pascui; André A de Souza; Tito J Bonagamba; Detlef Reichert
Journal:  J Chem Phys       Date:  2008-03-14       Impact factor: 3.488

Review 7.  Supramolecular ferroelectrics.

Authors:  Alok S Tayi; Adrien Kaeser; Michio Matsumoto; Takuzo Aida; Samuel I Stupp
Journal:  Nat Chem       Date:  2015-04       Impact factor: 24.427

8.  A metal-organic framework-based splitter for separating propylene from propane.

Authors:  A Cadiau; K Adil; P M Bhatt; Y Belmabkhout; M Eddaoudi
Journal:  Science       Date:  2016-07-08       Impact factor: 47.728

9.  Enhanced stability and CO2 affinity of a UiO-66 type metal-organic framework decorated with dimethyl groups.

Authors:  Yuting Huang; Weiping Qin; Zhong Li; Yingwei Li
Journal:  Dalton Trans       Date:  2012-07-05       Impact factor: 4.390

10.  Solid-state NMR: a powerful tool for characterization of metal-organic frameworks.

Authors:  Andre Sutrisno; Yining Huang
Journal:  Solid State Nucl Magn Reson       Date:  2012-10-17       Impact factor: 2.293

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  3 in total

Review 1.  Performance of Mixed Matrix Membranes Containing Porous Two-Dimensional (2D) and Three-Dimensional (3D) Fillers for CO₂ Separation: A Review.

Authors:  Mahdi Ahmadi; Saravanan Janakiram; Zhongde Dai; Luca Ansaloni; Liyuan Deng
Journal:  Membranes (Basel)       Date:  2018-07-28

2.  Atomistic Insight Into the Host-Guest Interaction of a Photoresponsive Metal-Organic Framework.

Authors:  Elena Kolodzeiski; Saeed Amirjalayer
Journal:  Chemistry       Date:  2020-01-21       Impact factor: 5.236

3.  Emergence of Coupled Rotor Dynamics in Metal-Organic Frameworks via Tuned Steric Interactions.

Authors:  Adrian Gonzalez-Nelson; Srinidhi Mula; Mantas Šimėnas; Sergejus Balčiu Nas; Adam R Altenhof; Cameron S Vojvodin; Stefano Canossa; Ju Ras Banys; Robert W Schurko; François-Xavier Coudert; Monique A van der Veen
Journal:  J Am Chem Soc       Date:  2021-07-29       Impact factor: 15.419

  3 in total

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