| Literature DB >> 29782692 |
Joshua T Damron1, Jialiu Ma1, Ricardo Kurz2, Kay Saalwächter2, Adam J Matzger1,3, Ayyalusamy Ramamoorthy1,4.
Abstract
The robust synthetic flexibility of metal-organic frameworks (MOFs) offers a promising class of tailorable materials, for which the ability to tune specific physicochemical properties is highly desired. This is achievable only through a thorough description of the consequences for chemical manipulations both in structure and dynamics. Magic angle spinning solid-state NMR spectroscopy offers many modalities in this pursuit, particularly for dynamic studies. Herein, we employ a separated-local-field NMR approach to show how specific intraframework chemical modifications to MOF UiO-66 heavily modulate the dynamic evolution of the organic ring moiety over several orders of magnitude.Entities:
Keywords: NMR spectroscopy; density functional theory; dynamics; metal-organic frameworks; microporous materials
Mesh:
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Year: 2018 PMID: 29782692 PMCID: PMC6289050 DOI: 10.1002/anie.201805004
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN: 1433-7851 Impact factor: 15.336