Donor-acceptor-type supramolecular polymers on the basis of preorganized molecular tweezers/guest complexation.

The bottom-up self-assembly of donor-acceptor (D-A) units has received tremendous attention in recent years. Charge-transfer interactions, which are inherently embedded in D-A pairs, have suffered from some disadvantages such as erratic arrangements and weak binding affinity, thus hampering the precise arrangement of D-A units into long-range-ordered supramolecular polymers. To address this issue, a feasible protocol is to incorporate D-A units into molecular tweezers/guest recognition motifs, which concurrently feature high complexation directionality, strong binding affinity and stimuli-responsiveness. In this tutorial review, we have summarized the recent advances on the tweezering directed formation of D-A-type supramolecular polymers, with particular emphasis on the design principles of monomers and macroscopic behaviors of supramolecular polymers, together with future challenges in this research field.