Literature DB >> 29729085

Palladium-Catalyzed Mizoroki-Heck-Type Alkenylation of Monoaryldialkylsulfoniums.

Daisuke Uno1, Hiroko Minami1, Shinya Otsuka1, Keisuke Nogi1, Hideki Yorimitsu1.   

Abstract

Mizoroki-Heck-type alkenylation of monoaryldialkylsulfoniums has been accomplished by means of palladium catalysts. Various combinations of monoarylsulfoniums and alkenes were adapted to the present reaction. Because monoaryldimethylsulfoniums were readily prepared from the corresponding aryl methyl sulfides and methyl triflate, one-pot alkenylation of aryl methyl sulfide could also be executed.
© 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  alkenes; alkenylation; aryl methyl sulfide; arylsulfonium; palladium

Year:  2018        PMID： 29729085     DOI： 10.1002/asia.201800489

Source DB:  PubMed          Journal:  Chem Asian J        ISSN： 1861-471X


  4 in total

1.  Bond-Forming and -Breaking Reactions at Sulfur(IV): Sulfoxides, Sulfonium Salts, Sulfur Ylides, and Sulfinate Salts.

Authors:  Daniel Kaiser; Immo Klose; Rik Oost; James Neuhaus; Nuno Maulide
Journal:  Chem Rev       Date:  2019-06-25       Impact factor: 60.622

2.  α-Diazo Sulfonium Triflates: Synthesis, Structure, and Application to the Synthesis of 1-(Dialkylamino)-1,2,3-triazoles.

Authors:  Xiangdong Li; Christopher Golz; Manuel Alcarazo
Journal:  Angew Chem Int Ed Engl       Date:  2021-02-17       Impact factor: 15.336

3.  Cu-Catalyzed Arylation of Bromo-Difluoro-Acetamides by Aryl Boronic Acids, Aryl Trialkoxysilanes and Dimethyl-Aryl-Sulfonium Salts: New Entries to Aromatic Amides.

Authors:  Satenik Mkrtchyan; Michał Jakubczyk; Suneel Lanka; Michael Pittelkow; Viktor O Iaroshenko
Journal:  Molecules       Date:  2021-05-16       Impact factor: 4.411

4.  Acetonitrile-Hexane Extraction Route to Pure Sulfonium Salts.

Authors:  Bilal Altundas; Chepuri V Suneel Kumar; Fraser F Fleming
Journal:  ACS Omega       Date:  2020-05-29
  4 in total

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