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Literature DB >> 29726550

Reductive C-C Coupling via Hydrogenation and Transfer Hydrogenation: Departure from Stoichiometric Metals in Carbonyl Addition.

James Roane¹, Michael Holmes¹, Michael J Krische¹.

Abstract

Metal catalyzed reductive couplings of π-unsaturated reagents with carbonyl compounds via hydrogenation or transfer hydrogenation has emerged as an alternative to the use of stoichiometric organometallic reagents in carbonyl addition.

Entities: Chemical Gene

Year: 2017 PMID： 29726550 PMCID： PMC5926236 DOI： 10.1016/j.cogsc.2017.06.006

Source DB: PubMed Journal: Curr Opin Green Sustain Chem

35 in total

1. Catalytic enantioselective allylation of carbonyl compounds and imines.

Authors: Miguel Yus; José C González-Gómez; Francisco Foubelo
Journal: Chem Rev Date: 2011-09-16 Impact factor: 60.622

Review 2. The importance of green chemistry in process research and development.

Authors: Peter J Dunn
Journal: Chem Soc Rev Date: 2011-05-12 Impact factor: 54.564

3. Unlocking Hydrogenation for C-C Bond Formation: A Brief Overview of Enantioselective Methods.

Authors: Abbas Hassan; Michael J Krische
Journal: Org Process Res Dev Date: 2011-11-18 Impact factor: 3.317

4. Paraformaldehyde and methanol as C1 feedstocks in metal-catalyzed C-C couplings of π-unsaturated reactants: beyond hydroformylation.

Authors: Brannon Sam; Bernhard Breit; Michael J Krische
Journal: Angew Chem Int Ed Engl Date: 2014-11-27 Impact factor: 15.336

5. Diastereo- and Enantioselective Iridium Catalyzed Coupling of Vinyl Aziridines with Alcohols: Site-Selective Modification of Unprotected Diols and Synthesis of Substituted Piperidines.

Authors: Gang Wang; Jana Franke; Chinh Q Ngo; Michael J Krische
Journal: J Am Chem Soc Date: 2015-06-15 Impact factor: 15.419

6. Regioselective Hydrohydroxyalkylation of Styrene with Primary Alcohols or Aldehydes via Ruthenium-Catalyzed C-C Bond Forming Transfer Hydrogenation.

Authors: Hongde Xiao; Gang Wang; Michael J Krische
Journal: Angew Chem Int Ed Engl Date: 2016-12-02 Impact factor: 15.336

Review 1. Intermolecular Metal-Catalyzed Reductive Coupling of Dienes, Allenes, and Enynes with Carbonyl Compounds and Imines.

Authors: Michael Holmes; Leyah A Schwartz; Michael J Krische
Journal: Chem Rev Date: 2018-06-13 Impact factor: 60.622

1 in total

Reductive C-C Coupling via Hydrogenation and Transfer Hydrogenation: Departure from Stoichiometric Metals in Carbonyl Addition.

1. Catalytic enantioselective allylation of carbonyl compounds and imines.

Review 2. The importance of green chemistry in process research and development.

3. Unlocking Hydrogenation for C-C Bond Formation: A Brief Overview of Enantioselective Methods.

4. Paraformaldehyde and methanol as C1 feedstocks in metal-catalyzed C-C couplings of π-unsaturated reactants: beyond hydroformylation.

5. Diastereo- and Enantioselective Iridium Catalyzed Coupling of Vinyl Aziridines with Alcohols: Site-Selective Modification of Unprotected Diols and Synthesis of Substituted Piperidines.

6. Regioselective Hydrohydroxyalkylation of Styrene with Primary Alcohols or Aldehydes via Ruthenium-Catalyzed C-C Bond Forming Transfer Hydrogenation.

7. Catalytic asymmetric synthesis of allylic alcohols and derivatives and their applications in organic synthesis.

Review 8. C-Alkylation of Ketones and Related Compounds by Alcohols: Transition-Metal-Catalyzed Dehydrogenation.

9. A Step into an eco-Compatible Future: Iron- and Cobalt-catalyzed Borrowing Hydrogen Transformation.

10. Catalytic enantioselective OFF ↔ ON activation processes initiated by hydrogen transfer: concepts and challenges.

Review 1. Intermolecular Metal-Catalyzed Reductive Coupling of Dienes, Allenes, and Enynes with Carbonyl Compounds and Imines.