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Literature DB >> 26666210

A Step into an eco-Compatible Future: Iron- and Cobalt-catalyzed Borrowing Hydrogen Transformation.

Abstract

Living on borrowed hydrogen: Recent developments in iron- and cobalt-catalyzed borrowing hydrogen have shown that economically reliable catalysts can be used in this type of waste-free reactions. By using well-defined inexpensive catalysts, known reactions can now be run efficiently without the necessary use of noble metals; however, in addition new types of reactivity can also be discovered.

Entities: Chemical

Keywords: cobalt; eco-compatibility; homogeneous catalysis; hydrogen transfer; iron

Mesh：

Substances：

Year: 2015 PMID： 26666210 DOI： 10.1002/cssc.201501460

Source DB: PubMed Journal: ChemSusChem ISSN： 1864-5631 Impact factor: 8.928

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Cited

11 in total

1. Carbonyl anti-(α-Amino)allylation via Ruthenium Catalyzed Hydrogen Autotransfer: Use of an Acetylenic Pyrrole as an Allylmetal Pronucleophile.

Authors: Wandi Zhang; Weijie Chen; Hongde Xiao; Michael J Krische
Journal: Org Lett Date: 2017-08-29 Impact factor: 6.005

2. Diols as Dienophiles: Bridged Carbocycles via Ruthenium(0)-Catalyzed Transfer Hydrogenative Cycloadditions of Cyclohexadiene or Norbornadiene.

Authors: Hiroki Sato; Keisuke Fukaya; Binit Sharma Poudel; Michael J Krische
Journal: Angew Chem Int Ed Engl Date: 2017-10-10 Impact factor: 15.336

3. Enantioselective Iridium-Catalyzed Phthalide Formation through Internal Redox Allylation of Phthalaldehydes.

Authors: James M Cabrera; Johannes Tauber; Michael J Krische
Journal: Angew Chem Int Ed Engl Date: 2018-01-04 Impact factor: 15.336

4. Catalytic Enantioselective Carbonyl Allylation and Propargylation via Alcohol-Mediated Hydrogen Transfer: Merging the Chemistry of Grignard and Sabatier.

Authors: Seung Wook Kim; Wandi Zhang; Michael J Krische
Journal: Acc Chem Res Date: 2017-08-09 Impact factor: 22.384

5. Reductive C-C Coupling via Hydrogenation and Transfer Hydrogenation: Departure from Stoichiometric Metals in Carbonyl Addition.

Authors: James Roane; Michael Holmes; Michael J Krische
Journal: Curr Opin Green Sustain Chem Date: 2017-06-09

A Step into an eco-Compatible Future: Iron- and Cobalt-catalyzed Borrowing Hydrogen Transformation.

1. Carbonyl anti-(α-Amino)allylation via Ruthenium Catalyzed Hydrogen Autotransfer: Use of an Acetylenic Pyrrole as an Allylmetal Pronucleophile.

2. Diols as Dienophiles: Bridged Carbocycles via Ruthenium(0)-Catalyzed Transfer Hydrogenative Cycloadditions of Cyclohexadiene or Norbornadiene.

3. Enantioselective Iridium-Catalyzed Phthalide Formation through Internal Redox Allylation of Phthalaldehydes.

4. Catalytic Enantioselective Carbonyl Allylation and Propargylation via Alcohol-Mediated Hydrogen Transfer: Merging the Chemistry of Grignard and Sabatier.

5. Reductive C-C Coupling via Hydrogenation and Transfer Hydrogenation: Departure from Stoichiometric Metals in Carbonyl Addition.

Review 6. Ruthenium(0)-Catalyzed Cycloaddition of 1,2-Diols, Ketols, or Diones via Alcohol-Mediated Hydrogen Transfer.

7. Development and mechanistic investigation of the manganese(iii) salen-catalyzed dehydrogenation of alcohols.

8. Iron-Catalyzed Borrowing Hydrogen C-Alkylation of Oxindoles with Alcohols.

9. Allylic alcohol synthesis by Ni-catalyzed direct and selective coupling of alkynes and methanol.

10. Unprecedented selective homogeneous cobalt-catalysed reductive alkoxylation of cyclic imides under mild conditions.