Literature DB >> 29712354

Insertion of Helium and Molecular Hydrogen Through the Orifice of an Open Fullerene.

Yves Rubin1, Thibaut Jarrosson1, Guan-Wu Wang2, Michael D Bartberger1, K N Houk1, Georg Schick1, Martin Saunders2, R James Cross2.   

Abstract

A "molecular surgery" approach has been used to create an opening within a fullerene cage that is large enough to allow atoms and small molecules to pass through. The thermodynamics for the insertion of He and H2 into the open fullerene (left and right pictures, respectively) as well as their escape have been studied by NMR spectroscopy and theoretical methods.
© 2001 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.

Entities:  

Keywords:  density functional calculations; fullerenes; helium; host-guest chemistry; hydrogen

Year:  2001        PMID： 29712354     DOI： 10.1002/1521-3773(20010417)40:8<1543::AID-ANIE1543>3.0.CO;2-6

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  4 in total

1.  Reversible Diels-Alder Addition to Fullerenes: A Study of Dimethylanthracene with H2@C60.

Authors:  Mahboob Subhani; Jinrong Zhou; Yuguang Sui; Huijing Zou; Michael Frunzi; James Cross; Martin Saunders; Cijun Shuai; Wenjie Liang; Hai Xu
Journal:  Nanomaterials (Basel)       Date:  2022-05-13       Impact factor: 5.719

2.  First Synthesis and Characterization of CH4 @C60.

Authors:  Sally Bloodworth; Gabriela Sitinova; Shamim Alom; Sara Vidal; George R Bacanu; Stuart J Elliott; Mark E Light; Julie M Herniman; G John Langley; Malcolm H Levitt; Richard J Whitby
Journal:  Angew Chem Int Ed Engl       Date:  2019-03-12       Impact factor: 15.336

3.  A Solid-State Intramolecular Wittig Reaction Enables Efficient Synthesis of Endofullerenes Including Ne@C60 , 3 He@C60 , and HD@C60.

Authors:  Gabriela Hoffman; Mark C Walkey; John Gräsvik; George R Bacanu; Shamim Alom; Sally Bloodworth; Mark E Light; Malcolm H Levitt; Richard J Whitby
Journal:  Angew Chem Int Ed Engl       Date:  2021-03-04       Impact factor: 15.336

4.  Vibronic Coupling in Spherically Encapsulated, Diatomic Molecules: Prediction of a Renner-Teller-like Effect for Endofullerenes.

Authors:  Andreas W Hauser; Johann V Pototschnig
Journal:  J Phys Chem A       Date:  2022-03-08       Impact factor: 2.944
  4 in total

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