Literature DB >> 29711340

A Novel Class of Ruthenium Catalysts for Olefin Metathesis.

Thomas Weskamp1, Wolfgang C Schattenmann1, Michael Spiegler1, Wolfgang A Herrmann1.   

Abstract

The different nature of carbene ligands is clearly demonstrated by the first ruthenium-based complexes 1, which contain both alkylidene and N-heterocyclic carbene moieties. The latter exhibit a pronounced Lewis base behavior. Moreover, this difference forms the basis of the high catalytic activities of these compounds in olefin metathesis reactions. © 1998 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.

Entities:  

Keywords:  Alkenes; Carbenes; Homogeneous catalysis; Metathesis; Ruthenium

Year:  1998        PMID： 29711340     DOI： 10.1002/(SICI)1521-3773(19981002)37:18<2490::AID-ANIE2490>3.0.CO;2-X

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  6 in total

1.  Orientation and stereodynamic paths of planar monodentate ligands in square planar nickel N2S complexes.

Authors:  Roxanne M Jenkins; Michael L Singleton; Lauren A Leamer; Joseph H Reibenspies; Marcetta Y Darensbourg
Journal:  Inorg Chem       Date:  2010-06-21       Impact factor: 5.165

2.  Visible-Light-Controlled Ruthenium-Catalyzed Olefin Metathesis.

Authors:  Cédric Theunissen; Melissa A Ashley; Tomislav Rovis
Journal:  J Am Chem Soc       Date:  2019-04-22       Impact factor: 15.419

3.  Mechanistic insights into the insertion and addition reactions of group 13 analogues of the six-membered N-heterocyclic carbenes: interplay of electrophilicity, basicity, and aromaticity governing the reactivity.

Authors:  Zheng-Feng Zhang; Ming-Der Su
Journal:  RSC Adv       Date:  2021-06-04       Impact factor: 4.036

4.  Correlation between the electronic/local structure and CO-oxidation activity of Pd x Ru1-x alloy nanoparticles.

Authors:  Chulho Song; Akhil Tayal; Okkyun Seo; Jaemyung Kim; Yanna Chen; Satoshi Hiroi; L S R Kumara; Kohei Kusada; Hirokazu Kobayashi; Hiroshi Kitagawa; Osami Sakata
Journal:  Nanoscale Adv       Date:  2018-12-19

Review 5.  Olefin metathesis in air.

Authors:  Lorenzo Piola; Fady Nahra; Steven P Nolan
Journal:  Beilstein J Org Chem       Date:  2015-10-30       Impact factor: 2.883

6.  Bis(Cyclic Alkyl Amino Carbene) Ruthenium Complexes: A Versatile, Highly Efficient Tool for Olefin Metathesis.

Authors:  Rafał Gawin; Anna Kozakiewicz; Piotr A Guńka; Paweł Dąbrowski; Krzysztof Skowerski
Journal:  Angew Chem Int Ed Engl       Date:  2016-12-12       Impact factor: 15.336
  6 in total

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