Literature DB >> 29711255

First Isolation and Structural Characterization of a Nickel(III) Complex Containing Aliphatic Thiolate Donors.

Jan Hanss1, Hans-Jörg Krüger1.   

Abstract

Long overdue were syntheses of nickel(III) complexes containing aliphatic thiolate ligands. The complex anion [Ni(phmi)]- (phmi is the tetraanion of N,N'-1,2-phenylenebis(2-methyl-2-sulfanylpropionamide) has now been isolated-as PPh4 salt-and structurally characterized. The stability of the nickel(III) complex is attributed to the special properties of the ligand, which abolish or at least retard possible decomposition pathways. © 1998 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.

Entities:  

Keywords:  High-valent metal ions; Nickel; Redox chemistry; S ligands

Year:  1998        PMID： 29711255     DOI： 10.1002/(SICI)1521-3773(19980216)37:3<360::AID-ANIE360>3.0.CO;2-P

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  3 in total

1.  Dipeptide-based models of nickel superoxide dismutase: solvent effects highlight a critical role to Ni-S bonding and active site stabilization.

Authors:  Eric M Gale; Darin M Cowart; Robert A Scott; Todd C Harrop
Journal:  Inorg Chem       Date:  2011-09-20       Impact factor: 5.165

2.  Bisamidate and mixed amine/amidate NiN2S2 complexes as models for nickel-containing acetyl coenzyme A synthase and superoxide dismutase: an experimental and computational study.

Authors:  Vaidyanathan Mathrubootham; Jason Thomas; Richard Staples; John McCraken; Jason Shearer; Eric L Hegg
Journal:  Inorg Chem       Date:  2010-06-21       Impact factor: 5.165

3.  Functional Conversion of Acetyl-Coenzyme a Synthase to a Nickel Superoxide Dismutase via Rational Design of Coordination Microenvironment for the Nid-Site.

Authors:  Yaozhu Wei; Yajun Zhou; Hong Yuan; Yi Liu; Ying-Wu Lin; Jihu Su; Xiangshi Tan
Journal:  Int J Mol Sci       Date:  2022-02-28       Impact factor: 5.923
  3 in total

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