Literature DB >> 29711172

The Weak-Link Approach to the Synthesis of Inorganic Macrocycles.

Joshua R Farrell1, Chad A Mirkin1, Ilia A Guzei2, Louise M Liable-Sands2, Arnold L Rheingold2.   

Abstract

Homobimetallic macrocycles are prepared from flexible ligands in high yield by means of a new and general synthetic strategy called the "weak-link approach" [Eq. (a)]. Small aromatic molecules can be aligned inside the cage based on their interactions with the two Rh centers of the macrocycle. © 1998 WILEY-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany.

Keywords:  Macrocycles; P ligands; Rhodium

Year:  1998        PMID: 29711172     DOI: 10.1002/(SICI)1521-3773(19980302)37:4<465::AID-ANIE465>3.0.CO;2-A

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN: 1433-7851            Impact factor:   15.336


  5 in total

1.  Chelating effect as a driving force for the selective formation of heteroligated Pt(II) complexes with bidentate phosphino-chalcoether ligands.

Authors:  Mari S Rosen; Alexander M Spokoyny; Charles W Machan; Charlotte Stern; Amy Sarjeant; Chad A Mirkin
Journal:  Inorg Chem       Date:  2010-12-28       Impact factor: 5.165

2.  Inversion of product selectivity in an enzyme-inspired metallosupramolecular tweezer catalyzed epoxidation reaction.

Authors:  Pirmin A Ulmann; Adam B Braunschweig; One-Sun Lee; Michael J Wiester; George C Schatz; Chad A Mirkin
Journal:  Chem Commun (Camb)       Date:  2009-07-16       Impact factor: 6.222

3.  Threefold symmetric trimetallic macrocycles formed via the Weak-Link Approach.

Authors:  Maxim V Ovchinnikov; Bradley J Holliday; Chad A Mirkin; Lev N Zakharov; Arnold L Rheingold
Journal:  Proc Natl Acad Sci U S A       Date:  2002-04-09       Impact factor: 11.205

4.  Heteroligated supramolecular coordination complexes formed via the halide-induced ligand rearrangement reaction.

Authors:  Christopher G Oliveri; Pirmin A Ulmann; Michael J Wiester; Chad A Mirkin
Journal:  Acc Chem Res       Date:  2008-12       Impact factor: 22.384

Review 5.  Structural Flexibility in Metal-Organic Cages.

Authors:  Andrés E Martín Díaz; James E M Lewis
Journal:  Front Chem       Date:  2021-06-17       Impact factor: 5.221

  5 in total

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