Literature DB >> 20448966

Inversion of product selectivity in an enzyme-inspired metallosupramolecular tweezer catalyzed epoxidation reaction.

Pirmin A Ulmann1, Adam B Braunschweig, One-Sun Lee, Michael J Wiester, George C Schatz, Chad A Mirkin.   

Abstract

This study describes a heteroligated, hemilabile Pt(II)-P,S tweezer coordination complex that combines a chiral Jacobsen-Katsuki Mn(III)-salen epoxidation catalyst with an amidopyridine receptor, which leads to an inversion of the major epoxide product compared to catalysts without a recognition group.

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Year:  2009        PMID： 20448966      PMCID： PMC3930335          DOI： 10.1039/b908852k

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  25 in total

1.  Strategies for the Construction of Supramolecular Compounds through Coordination Chemistry.

Authors:  Bradley J. Holliday; Chad A. Mirkin
Journal:  Angew Chem Int Ed Engl       Date:  2001-06-01       Impact factor: 15.336

2.  Self-assembly of discrete cyclic nanostructures mediated by transition metals.

Authors:  S Leininger; B Olenyuk; P J Stang
Journal:  Chem Rev       Date:  2000-03-08       Impact factor: 60.622

3.  Epoxidation of polybutadiene by a topologically linked catalyst.

Authors:  Pall Thordarson; Edward J A Bijsterveld; Alan E Rowan; Roeland J M Nolte
Journal:  Nature       Date:  2003-08-21       Impact factor: 49.962

4.  Development of a coordination chemistry-based approach for functional supramolecular structures.

Authors:  Nathan C Gianneschi; Martin S Masar; Chad A Mirkin
Journal:  Acc Chem Res       Date:  2005-11       Impact factor: 22.384

5.  Selective molecular recognition, C-H bond activation, and catalysis in nanoscale reaction vessels.

Authors:  Dorothea Fiedler; Dennis H Leung; Robert G Bergman; Kenneth N Raymond
Journal:  Acc Chem Res       Date:  2005-04       Impact factor: 22.384

6.  Systems chemistry: kinetic and computational analysis of a nearly exponential organic replicator.

Authors:  Maik Kindermann; Insa Stahl; Malte Reimold; Wolf Matthias Pankau; Günter von Kiedrowski
Journal:  Angew Chem Int Ed Engl       Date:  2005-10-21       Impact factor: 15.336

7.  A dynamic supramolecular system exhibiting substrate selectivity in the catalytic epoxidation of olefins.

Authors:  Stefán Jónsson; Fabrice G J Odille; Per-Ola Norrby; Kenneth Wärnmark
Journal:  Chem Commun (Camb)       Date:  2004-12-02       Impact factor: 6.222

8.  The productive conformation of arachidonic acid bound to prostaglandin synthase.

Authors:  M G Malkowski; S L Ginell; W L Smith; R M Garavito
Journal:  Science       Date:  2000-09-15       Impact factor: 47.728

9.  Halide-induced supramolecular ligand rearrangement.

Authors:  Aaron M Brown; Maxim V Ovchinnikov; Charlotte L Stern; Chad A Mirkin
Journal:  J Am Chem Soc       Date:  2004-11-10       Impact factor: 15.419

10.  Donor ligand effect on the nature of the oxygenating species in Mn(III)(salen)-catalyzed epoxidation of olefins: experimental evidence for multiple active oxidants.

Authors:  James P Collman; Li Zeng; John I Brauman
Journal:  Inorg Chem       Date:  2004-04-19       Impact factor: 5.165
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  3 in total

1.  Solvent and temperature induced switching between structural isomers of Rh(I) phosphinoalkyl thioether (PS) complexes.

Authors:  Michael J Wiester; Adam B Braunschweig; Hyojong Yoo; Chad A Mirkin
Journal:  Inorg Chem       Date:  2010-08-02       Impact factor: 5.165

2.  Coordination-driven self-assembly of M3L2 trigonal cages from preorganized metalloligands incorporating octahedral metal centers and fluorescent detection of nitroaromatics.

Authors:  Ming Wang; Vaishali Vajpayee; Sankarasekaran Shanmugaraju; Yao-Rong Zheng; Zhigang Zhao; Hyunuk Kim; Partha Sarathi Mukherjee; Ki-Whan Chi; Peter J Stang
Journal:  Inorg Chem       Date:  2011-01-07       Impact factor: 5.165

3.  Construction of endo-functionalized two dimensional metallacycles via coordination-driven self-assembly.

Authors:  Liang Zhao; Koushik Ghosh; Yao-Rong Zheng; Peter J Stang
Journal:  J Org Chem       Date:  2009-11-20       Impact factor: 4.354
  3 in total

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