Literature DB >> 29662252

Scalable Synthesis of Hydrido-Disiloxanes from Silanes: A One-Pot Preparation of 1,3-Diphenyldisiloxane from Phenylsilane.

Joseph A Buonomo1, Carter G Eiden1, Courtney C Aldrich1.   

Abstract

A simple, one-pot, and high-yielding synthesis of 1,3-diphenyldisiloxane is presented. The preparation of similar symmetrical disiloxane materials is also accomplished with this same protocol. This mechano-chemical procedure is efficient and highly scalable, furnishing a convenient route to hydrido-disiloxanes from widely accessible commercially available silanes.

Entities:  

Keywords:  ball-milling; chlorination; copper; one-pot; silane; siloxane

Year:  2017        PMID： 29662252      PMCID： PMC5898624          DOI： 10.1055/s-0036-1588580

Source DB:  PubMed          Journal:  Synthesis (Stuttg)        ISSN： 0039-7881            Impact factor:   3.157


  17 in total

1.  Rhodium carbene complexes as versatile catalyst precursors for Si-H bond activation.

Authors:  Anneke Krüger; Martin Albrecht
Journal:  Chemistry       Date:  2011-12-08       Impact factor: 5.236

2.  Surface oxygen-assisted Pd nanoparticle catalysis for selective oxidation of silanes to silanols.

Authors:  Ken-ichi Shimizu; Takahiro Kubo; Atsushi Satsuma
Journal:  Chemistry       Date:  2012-01-25       Impact factor: 5.236

3.  Hydrogen production from hydrolytic oxidation of organosilanes using a cationic oxorhenium catalyst.

Authors:  Elon A Ison; Rex A Corbin; Mahdi M Abu-Omar
Journal:  J Am Chem Soc       Date:  2005-08-31       Impact factor: 15.419

Review 4.  Reduction of secondary and tertiary phosphine oxides to phosphines.

Authors:  Damien Hérault; Duc Hanh Nguyen; Didier Nuel; Gérard Buono
Journal:  Chem Soc Rev       Date:  2015-04-21       Impact factor: 54.564

5.  A phosphetane catalyzes deoxygenative condensation of α-keto esters and carboxylic acids via P(III)/P(V)═O redox cycling.

Authors:  Wei Zhao; Patrick K Yan; Alexander T Radosevich
Journal:  J Am Chem Soc       Date:  2015-01-13       Impact factor: 15.419

6.  Chemoselective Reduction of Phosphine Oxides by 1,3-Diphenyl-Disiloxane.

Authors:  Joseph A Buonomo; Carter G Eiden; Courtney C Aldrich
Journal:  Chemistry       Date:  2017-09-18       Impact factor: 5.236

7.  From carbon dioxide to methane: homogeneous reduction of carbon dioxide with hydrosilanes catalyzed by zirconium-borane complexes.

Authors:  Tsukasa Matsuo; Hiroyuki Kawaguchi
Journal:  J Am Chem Soc       Date:  2006-09-27       Impact factor: 15.419

8.  Disiloxane Synthesis Based on Silicon-Hydrogen Bond Activation using Gold and Platinum on Carbon in Water or Heavy Water.

Authors:  Yoshinari Sawama; Masahiro Masuda; Naoki Yasukawa; Ryosuke Nakatani; Shumma Nishimura; Kyoshiro Shibata; Tsuyoshi Yamada; Yasunari Monguchi; Hiroyasu Suzuka; Yukio Takagi; Hironao Sajiki
Journal:  J Org Chem       Date:  2016-05-10       Impact factor: 4.354

9.  Highly efficient iridium-catalyzed oxidation of organosilanes to silanols.

Authors:  Youngjun Lee; Dong Seomoon; Sundae Kim; Hoon Han; Sukbok Chang; Phil Ho Lee
Journal:  J Org Chem       Date:  2004-03-05       Impact factor: 4.354

10.  Mitsunobu Reactions Catalytic in Phosphine and a Fully Catalytic System.

Authors:  Joseph A Buonomo; Courtney C Aldrich
Journal:  Angew Chem Int Ed Engl       Date:  2015-09-08       Impact factor: 15.336
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  1 in total

1.  The Power of Chemists Is in What They Can Learn, Not What They Already Know.

Authors:  Joseph A Buonomo
Journal:  Chembiochem       Date:  2020-11-04       Impact factor: 3.164
  1 in total

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