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Literature DB >> 14987039

Highly efficient iridium-catalyzed oxidation of organosilanes to silanols.

Youngjun Lee¹, Dong Seomoon, Sundae Kim, Hoon Han, Sukbok Chang, Phil Ho Lee.

Abstract

Hydrolytic oxidation of organosilanes to the corresponding silanols can be performed highly efficiently with a catalyst system of [IrCl(C(8)H(12))](2) under essentially neutral and mild conditions, and various types of silanols are produced in good to excellent yields.

Entities: Chemical

Year: 2004 PMID： 14987039 DOI： 10.1021/jo035647r

Source DB: PubMed Journal: J Org Chem ISSN： 0022-3263 Impact factor: 4.354

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Cited

7 in total

1. Total Synthesis of (+)-Papulacandin D.

Authors: Scott E Denmark; Tetsuya Kobayashi; Christopher S Regens
Journal: Tetrahedron Date: 2010-06-26 Impact factor: 2.457

2. NHC-catalyzed dehydrogenative self-coupling of diphenylsilane: A facile synthesis of octaphenylcyclotetra(siloxane).

Authors: Abigail Albright; Robert E Gawley
Journal: Tetrahedron Lett Date: 2011-11-16 Impact factor: 2.415

3. Scalable Synthesis of Hydrido-Disiloxanes from Silanes: A One-Pot Preparation of 1,3-Diphenyldisiloxane from Phenylsilane.

Authors: Joseph A Buonomo; Carter G Eiden; Courtney C Aldrich
Journal: Synthesis (Stuttg) Date: 2017-09-26 Impact factor: 3.157

4. Development of Chiral Bis-hydrazone Ligands for the Enantioselective Cross-Coupling Reactions of Aryldimethylsilanolates.

Authors: Scott E Denmark; Wen-Tau T Chang; K N Houk; Peng Liu
Journal: J Org Chem Date: 2014-12-10 Impact factor: 4.354

Highly efficient iridium-catalyzed oxidation of organosilanes to silanols.

1. Total Synthesis of (+)-Papulacandin D.

2. NHC-catalyzed dehydrogenative self-coupling of diphenylsilane: A facile synthesis of octaphenylcyclotetra(siloxane).

3. Scalable Synthesis of Hydrido-Disiloxanes from Silanes: A One-Pot Preparation of 1,3-Diphenyldisiloxane from Phenylsilane.

4. Development of Chiral Bis-hydrazone Ligands for the Enantioselective Cross-Coupling Reactions of Aryldimethylsilanolates.

5. Selective Enzymatic Oxidation of Silanes to Silanols.

6. Cross-coupling reactions of aromatic and heteroaromatic silanolates with aromatic and heteroaromatic halides.

7. Hydrogen Tunneling in Catalytic Hydrolysis and Alcoholysis of Silanes.