| Literature DB >> 29625011 |
Li-Jun Chen1, Shangjun Chen2, Yi Qin1, Lin Xu1, Guang-Qiang Yin1,3, Jun-Long Zhu1, Fan-Fan Zhu1, Wei Zheng1, Xiaopeng Li3, Hai-Bo Yang1.
Abstract
The successful construction of porphyrin functionalized metallacycle in the confined cavity of mesoporous carbon FDU-16 (3⊂C) is presented in this study. Because of high dispersity of metallacycles within the mesoporous cavities, the stability and activity of porphyrin-containing metallacycles were obviously improved. For example, 1O2 generation efficiency of 3⊂C is ca. 6-fold faster than that of free metallaycles in solution. Thus, the resultant hybrid material has been successfully employed as a heterogeneous catalyst for photooxidation of sulfides.Entities:
Year: 2018 PMID: 29625011 DOI: 10.1021/jacs.8b02386
Source DB: PubMed Journal: J Am Chem Soc ISSN: 0002-7863 Impact factor: 15.419