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Literature DB >> 29573181

Recent Advances in Imidazoliumyl-Substituted Phosphorus Compounds.

Kai Schwedtmann¹, Giuseppe Zanoni², Jan J Weigand^1,2.

Abstract

This review aims to highlight the recent developments in the chemistry of selected imidazoliumyl-substituted phosphorus compounds. The synthetic approaches for their preparation with phosphorus in various oxidation states and coordination environments are discussed. Their intriguing properties and versatile chemistry strongly depends on the bonding motif at the P atoms, which is given special focus.

Entities: Chemical Disease

Keywords: N-heterocyclic carbenes; coordination chemistry; imidazoliumyl substituents; phosphorus; phosphorus-centered cations

Year: 2018 PMID： 29573181 DOI： 10.1002/asia.201800199

Source DB: PubMed Journal: Chem Asian J ISSN： 1861-471X

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Cited

7 in total

Recent Advances in Imidazoliumyl-Substituted Phosphorus Compounds.

1. Interconversion of Phosphinyl Radical and Phosphinidene Complexes by Proton Coupled Electron Transfer.

2. P-P Condensation and P-N/P-P Bond Metathesis: Facile Synthesis of Cationic Tri- and Tetraphosphanes.

3. Low-Valent Group 14 Phosphinidenide Complexes [({SIDipp}P)₂ M] Exhibit P-M pπ-pπ Interaction (M=Ge, Sn, Pb).

Review 4. Functionalization of Pentaphosphorus Cations by Complexation.

5. Isoselective Polymerization of rac-Lactide by Aluminum Complexes of N-Heterocyclic Carbene-Phosphinidene Adducts.

6. N-Heterocyclic Carbenes Carrying Weakly Coordinating Anions.

7. Rhodium and Iridium Complexes of Anionic Thione and Selone Ligands Derived from Anionic N-Heterocyclic Carbenes.

Recent Advances in Imidazoliumyl-Substituted Phosphorus Compounds.

1. Interconversion of Phosphinyl Radical and Phosphinidene Complexes by Proton Coupled Electron Transfer.

2. P-P Condensation and P-N/P-P Bond Metathesis: Facile Synthesis of Cationic Tri- and Tetraphosphanes.

3. Low-Valent Group 14 Phosphinidenide Complexes [({SIDipp}P)2 M] Exhibit P-M pπ-pπ Interaction (M=Ge, Sn, Pb).

Review 4. Functionalization of Pentaphosphorus Cations by Complexation.

5. Isoselective Polymerization of rac-Lactide by Aluminum Complexes of N-Heterocyclic Carbene-Phosphinidene Adducts.

6. N-Heterocyclic Carbenes Carrying Weakly Coordinating Anions.

7. Rhodium and Iridium Complexes of Anionic Thione and Selone Ligands Derived from Anionic N-Heterocyclic Carbenes.

3. Low-Valent Group 14 Phosphinidenide Complexes [({SIDipp}P)₂ M] Exhibit P-M pπ-pπ Interaction (M=Ge, Sn, Pb).