Literature DB >> 29465227

Synthesis and Applications of Perfunctionalized Boron Clusters.

Jonathan C Axtell1, Liban M A Saleh1, Elaine A Qian1,2,3, Alex I Wixtrom1, Alexander M Spokoyny1,3.   

Abstract

This Viewpoint describes major advances pertaining to perfunctionalized boron clusters in synthesis and their respective applications. The first portion of this work highlights key synthetic methods, allowing one to access a wide range of polyhedral boranes (B4 and B6-B12 cluster cores) that contain exhaustively functionalized vertices. The second portion of this Viewpoint showcases the historical developments in using these molecules for applications ranging from materials science to medicine. Last, we suggest potential new directions for these clusters as they apply to both synthetic methods and applications.

Entities:  

Year:  2018        PMID： 29465227      PMCID： PMC5985200          DOI： 10.1021/acs.inorgchem.7b02912

Source DB:  PubMed          Journal:  Inorg Chem        ISSN： 0020-1669            Impact factor:   5.165


  88 in total

1.  Direct perfluorination of K(2)B(12)H(12) in acetonitrile occurs at the gas bubble-solution interface and is inhibited by HF. Experimental and DFT study of inhibition by protic acids and soft, polarizable anions.

Authors:  Dmitry V Peryshkov; Alexey A Popov; Steven H Strauss
Journal:  J Am Chem Soc       Date:  2009-12-30       Impact factor: 15.419

2.  Sequence-Dependent Materials.

Authors:  Thomas M Osborn Popp; Omar M Yaghi
Journal:  Acc Chem Res       Date:  2017-03-21       Impact factor: 22.384

3.  Exhaustive chlorination of [B12H12]2- without chlorine gas and the use of [B12Cl12]2- as a Supporting anion in catalytic hydrodefluorination of aliphatic C-F bonds.

Authors:  Weixing Gu; Oleg V Ozerov
Journal:  Inorg Chem       Date:  2011-03-01       Impact factor: 5.165

Review 4.  Boron neutron capture therapy of cancer: current status and future prospects.

Authors:  Rolf F Barth; Jeffrey A Coderre; M Graça H Vicente; Thomas E Blue
Journal:  Clin Cancer Res       Date:  2005-06-01       Impact factor: 12.531

5.  High-field 13C dynamic nuclear polarization with a radical mixture.

Authors:  Vladimir K Michaelis; Albert A Smith; Björn Corzilius; Olesya Haze; Timothy M Swager; Robert G Griffin
Journal:  J Am Chem Soc       Date:  2013-02-13       Impact factor: 15.419

6.  Visible-Light-Induced Olefin Activation Using 3D Aromatic Boron-Rich Cluster Photooxidants.

Authors:  Marco S Messina; Jonathan C Axtell; Yiqun Wang; Paul Chong; Alex I Wixtrom; Kent O Kirlikovali; Brianna M Upton; Bryan M Hunter; Oliver S Shafaat; Saeed I Khan; Jay R Winkler; Harry B Gray; Anastassia N Alexandrova; Heather D Maynard; Alexander M Spokoyny
Journal:  J Am Chem Soc       Date:  2016-05-26       Impact factor: 15.419

7.  On the oxidation of the three-dimensional aromatics [B(12)X(12)](2-) (X=F, Cl, Br, I).

Authors:  René T Boeré; Janis Derendorf; Carsten Jenne; Sylwia Kacprzak; Mathias Kessler; Rainer Riebau; Sebastian Riedel; Tracey L Roemmele; Monika Rühle; Harald Scherer; Thomas Vent-Schmidt; Jonas Warneke; Stefan Weber
Journal:  Chemistry       Date:  2014-03-05       Impact factor: 5.236

8.  Synthesis and properties of the weakly coordinating anion [Me3 NB12 Cl11 ](-).

Authors:  Christoph Bolli; Janis Derendorf; Carsten Jenne; Harald Scherer; Christian P Sindlinger; Bianca Wegener
Journal:  Chemistry       Date:  2014-09-04       Impact factor: 5.236

9.  Update 1 of: Chemistry of the carba-closo-dodecaborate(-) anion, CB11H12(-).

Authors:  Christos Douvris; Josef Michl
Journal:  Chem Rev       Date:  2013-08-14       Impact factor: 60.622

10.  Application of boronated anti-CEA immunoliposome to tumour cell growth inhibition in in vitro boron neutron capture therapy model.

Authors:  H Yanagië; T Tomita; H Kobayashi; Y Fujii; T Takahashi; K Hasumi; H Nariuchi; M Sekiguchi
Journal:  Br J Cancer       Date:  1991-04       Impact factor: 7.640
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  20 in total

1.  Dynamic Nuclear Polarization Using 3D Aromatic Boron Cluster Radicals.

Authors:  Yaewon Kim; Rebecca Kubena; Jonathan Axtell; Hamidreza Samouei; Pierce Pham; Julia M Stauber; Alexander M Spokoyny; Christian Hilty
Journal:  J Phys Chem Lett       Date:  2020-12-09       Impact factor: 6.475

2.  Tuning the electrochemical potential of perfunctionalized dodecaborate clusters through vertex differentiation.

Authors:  Alex I Wixtrom; Zeeshan A Parvez; Miles D Savage; Elaine A Qian; Dahee Jung; Saeed I Khan; Arnold L Rheingold; Alexander M Spokoyny
Journal:  Chem Commun (Camb)       Date:  2018-06-05       Impact factor: 6.222

3.  Metal-catalyzed cross-coupling chemistry with polyhedral boranes.

Authors:  Rafal M Dziedzic; Alexander M Spokoyny
Journal:  Chem Commun (Camb)       Date:  2019-01-03       Impact factor: 6.222

4.  Therapeutic Effects of Newly Synthesized Boron Compounds (BGM and BGD) on Hepatocellular Carcinoma.

Authors:  Meliha Koldemir Gündüz; Melda Bolat; Güllü Kaymak; Derya Berikten; Dursun Ali Köse
Journal:  Biol Trace Elem Res       Date:  2021-02-26       Impact factor: 3.738

5.  Perfunctionalized Dodecaborate Clusters as Stable Metal-Free Active Materials for Charge Storage.

Authors:  John L Barton; Alex I Wixtrom; Jeffrey A Kowalski; Elaine A Qian; Dahee Jung; Fikile R Brushett; Alexander M Spokoyny
Journal:  ACS Appl Energy Mater       Date:  2019-06-06

6.  Sterically Unprotected Nucleophilic Boron Cluster Reagents.

Authors:  Xin Mu; Jonathan C Axtell; Nicholas A Bernier; Kent O Kirlikovali; Dahee Jung; Alexander Umanzor; Kevin Qian; Xiangyang Chen; Katherine L Bay; Monica Kirollos; Arnold L Rheingold; K N Houk; Alexander M Spokoyny
Journal:  Chem       Date:  2019-08-22       Impact factor: 22.804

7.  An Organometallic Strategy for Assembling Atomically Precise Hybrid Nanomaterials.

Authors:  Julia M Stauber; Elaine A Qian; Yanxiao Han; Arnold L Rheingold; Petr Král; Daishi Fujita; Alexander M Spokoyny
Journal:  J Am Chem Soc       Date:  2019-12-18       Impact factor: 15.419

8.  Gold(III) Aryl Complexes as Reagents for Constructing Hybrid Peptide-Based Assemblies via Cysteine S-Arylation.

Authors:  Julia M Stauber; Arnold L Rheingold; Alexander M Spokoyny
Journal:  Inorg Chem       Date:  2021-03-19       Impact factor: 5.165

9.  Unusual features of nitrogen substitutions in silicene.

Authors:  Hai Duong Pham; Godfrey Gumbs; Wu-Pei Su; Ngoc Thanh Thuy Tran; Ming-Fa Lin
Journal:  RSC Adv       Date:  2020-09-01       Impact factor: 4.036

10.  Theoretical Prediction of Structures, Vibrational Circular Dichroism, and Infrared Spectra of Chiral Be4B8 Cluster at Different Temperatures.

Authors:  Carlos Emiliano Buelna-García; Eduardo Robles-Chaparro; Tristan Parra-Arellano; Jesus Manuel Quiroz-Castillo; Teresa Del-Castillo-Castro; Gerardo Martínez-Guajardo; Cesar Castillo-Quevedo; Aned de-León-Flores; Gilberto Anzueto-Sánchez; Martha Fabiola Martin-Del-Campo-Solis; Ana Maria Mendoza-Wilson; Alejandro Vásquez-Espinal; Jose Luis Cabellos
Journal:  Molecules       Date:  2021-06-28       Impact factor: 4.411
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