Literature DB >> 29398711

Photocatalytic C-F Reduction and Functionalization.

Sameera Senaweera1, Jimmie D Weaver1.   

Abstract

Functionalized polyfluorinated aromatics have become an important group of molecules for pharmaceutical and industrial applications. However, facile access to such valuable molecules remains an unmet challenge. In this review, we present and discuss photocatalytic C-F functionalization, which is emerging as a straightforward and operationally simple path to access partially fluorinated aromatics.

Entities:  

Keywords:  C–F functionalization; hydrodefluorination; partially fluorinated aromatics; photocatalysis

Year:  2016        PMID: 29398711      PMCID: PMC5796778     

Source DB:  PubMed          Journal:  Aldrichimica Acta        ISSN: 0002-5100            Impact factor:   3.667


  46 in total

1.  Palladium(II)-catalyzed selective monofluorination of benzoic acids using a practical auxiliary: a weak-coordination approach.

Authors:  Kelvin S L Chan; Masayuki Wasa; Xisheng Wang; Jin-Quan Yu
Journal:  Angew Chem Int Ed Engl       Date:  2011-07-11       Impact factor: 15.336

2.  Synthesis of fluorinated building blocks by transition-metal-mediated hydrodefluorination reactions.

Authors:  Moritz F Kuehnel; Dieter Lentz; Thomas Braun
Journal:  Angew Chem Int Ed Engl       Date:  2013-01-25       Impact factor: 15.336

Review 3.  Visible light photoredox catalysis with transition metal complexes: applications in organic synthesis.

Authors:  Christopher K Prier; Danica A Rankic; David W C MacMillan
Journal:  Chem Rev       Date:  2013-03-19       Impact factor: 60.622

4.  A new palladium precatalyst allows for the fast Suzuki-Miyaura coupling reactions of unstable polyfluorophenyl and 2-heteroaryl boronic acids.

Authors:  Tom Kinzel; Yong Zhang; Stephen L Buchwald
Journal:  J Am Chem Soc       Date:  2010-10-13       Impact factor: 15.419

5.  Nickel-catalyzed monosubstitution of polyfluoroarenes with organozinc reagents using alkoxydiphosphine ligand.

Authors:  Yuki Nakamura; Naohiko Yoshikai; Laurean Ilies; Eiichi Nakamura
Journal:  Org Lett       Date:  2012-06-12       Impact factor: 6.005

6.  Copper-mediated fluorination of arylboronate esters. Identification of a copper(III) fluoride complex.

Authors:  Patrick S Fier; Jingwei Luo; John F Hartwig
Journal:  J Am Chem Soc       Date:  2013-02-05       Impact factor: 15.419

Review 7.  Fluorine in pharmaceutical industry: fluorine-containing drugs introduced to the market in the last decade (2001-2011).

Authors:  Jiang Wang; María Sánchez-Roselló; José Luis Aceña; Carlos del Pozo; Alexander E Sorochinsky; Santos Fustero; Vadim A Soloshonok; Hong Liu
Journal:  Chem Rev       Date:  2013-12-03       Impact factor: 60.622

8.  Catalytic activation of carbon-fluorine bonds by a soluble transition metal complex.

Authors:  M Aizenberg; D Milstein
Journal:  Science       Date:  1994-07-15       Impact factor: 47.728

9.  Tailoring atropisomeric maleimides for stereospecific [2 + 2] photocycloaddition--photochemical and photophysical investigations leading to visible-light photocatalysis.

Authors:  Elango Kumarasamy; Ramya Raghunathan; Steffen Jockusch; Angel Ugrinov; J Sivaguru
Journal:  J Am Chem Soc       Date:  2014-06-09       Impact factor: 15.419

10.  Photocatalyst size controls electron and energy transfer: selectable E/Z isomer synthesis via C-F alkenylation.

Authors:  A Singh; C J Fennell; J D Weaver
Journal:  Chem Sci       Date:  2016-07-21       Impact factor: 9.825

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  1 in total

1.  Selective and Scalable Perfluoroarylation of Nitroalkanes.

Authors:  Jon I Day; Jimmie D Weaver
Journal:  J Org Chem       Date:  2017-06-09       Impact factor: 4.354

  1 in total

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