Literature DB >> 29335701

A mononuclear manganese(iii)-hydroperoxo complex: synthesis by activating dioxygen and reactivity in electrophilic and nucleophilic reactions.

Muniyandi Sankaralingam1, Yong-Min Lee, So Hyun Jeon, Mi Sook Seo, Kyung-Bin Cho, Wonwoo Nam.   

Abstract

We report the synthesis of manganese(iii)-peroxo (MnIII(O2)) and manganese(iii)-hydroperoxo (MnIII(O2H)) complexes by activating dioxygen (O2) and the amphoteric reactivity of the Mn(iii)-hydroperoxo complex in electrophilic and nucleophilic reactions.

Entities:  

Year:  2018        PMID： 29335701     DOI： 10.1039/c7cc09492b

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

1.  MnIII-Peroxo adduct supported by a new tetradentate ligand shows acid-sensitive aldehyde deformylation reactivity.

Authors:  Melissa C Denler; Gayan B Wijeratne; Derek B Rice; Hannah E Colmer; Victor W Day; Timothy A Jackson
Journal:  Dalton Trans       Date:  2018-10-02       Impact factor: 4.390

2.  Oxidative Cleavage of Alkenes by O2 with a Non-Heme Manganese Catalyst.

Authors:  Zhiliang Huang; Renpeng Guan; Muralidharan Shanmugam; Elliot L Bennett; Craig M Robertson; Adam Brookfield; Eric J L McInnes; Jianliang Xiao
Journal:  J Am Chem Soc       Date:  2021-06-23       Impact factor: 15.419

3.  Formation of cobalt-oxygen intermediates by dioxygen activation at a mononuclear nonheme cobalt(ii) center.

Authors:  Deesha D Malik; Anirban Chandra; Mi Sook Seo; Yong-Min Lee; Erik R Farquhar; Stefan Mebs; Holger Dau; Kallol Ray; Wonwoo Nam
Journal:  Dalton Trans       Date:  2021-08-10       Impact factor: 4.569
  3 in total

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