Literature DB >> 29299550

Catalytic aziridination with alcoholic substrates via a chromium tetracarbene catalyst.

C Luke Keller1, Jesse L Kern, Bradley D Terry, Sharani Roy, David M Jenkins.   

Abstract

The first examples of aziridination catalysis with a chromium complex are communicated. This tetracarbene chromium complex provides novel catalytic aziridination reactions with protic substrates such as alcohols or amines on the alkene or organic azide and is the most effective catalyst at low alkene loading for aliphatic alkenes to date.

Entities:  

Year:  2018        PMID： 29299550      PMCID： PMC6136250          DOI： 10.1039/c7cc08928g

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  26 in total

1.  Mechanism of catalytic aziridination with manganese corrole: the often postulated high-valent Mn(V) imido is not the group transfer reagent.

Authors:  Michael J Zdilla; Mahdi M Abu-Omar
Journal:  J Am Chem Soc       Date:  2006-12-27       Impact factor: 15.419

2.  Probing the role of an Fe(IV) tetrazene in catalytic aziridination.

Authors:  S Alan Cramer; Raúl Hernández Sánchez; Desirae F Brakhage; David M Jenkins
Journal:  Chem Commun (Camb)       Date:  2014-11-21       Impact factor: 6.222

Review 3.  Recent advances in the stereoselective synthesis of aziridines.

Authors:  Leonardo Degennaro; Piera Trinchera; Renzo Luisi
Journal:  Chem Rev       Date:  2014-05-13       Impact factor: 60.622

4.  The chemistry of transition metals with three-membered ring heterocycles.

Authors:  Chung-Yang Dennis Huang; Abigail G Doyle
Journal:  Chem Rev       Date:  2014-05-28       Impact factor: 60.622

5.  Stereospecific Copper-Catalyzed Domino Ring Opening and sp3 C-H Functionalization of Activated Aziridines with N-Alkylanilines.

Authors:  Mani Sengoden; Abhisikta Bhowmick; Tharmalingam Punniyamurthy
Journal:  Org Lett       Date:  2016-12-15       Impact factor: 6.005

6.  Direct stereospecific synthesis of unprotected N-H and N-Me aziridines from olefins.

Authors:  Jawahar L Jat; Mahesh P Paudyal; Hongyin Gao; Qing-Long Xu; Muhammed Yousufuddin; Deepa Devarajan; Daniel H Ess; László Kürti; John R Falck
Journal:  Science       Date:  2014-01-03       Impact factor: 47.728

7.  Catalytic C-H bond amination from high-spin iron imido complexes.

Authors:  Evan R King; Elisabeth T Hennessy; Theodore A Betley
Journal:  J Am Chem Soc       Date:  2011-03-15       Impact factor: 15.419

8.  Multicomponent cis- and trans-Aziridinatons in the Syntheses of All Four Stereoisomers of Sphinganine.

Authors:  Yubai Zhou; Munmun Mukherjee; Anil K Gupta; William D Wulff
Journal:  Org Lett       Date:  2017-04-18       Impact factor: 6.005

9.  Copper(I)-Catalyzed Kinetic Resolution of N-Sulfonylaziridines with Indoles: Efficient Construction of Pyrroloindolines.

Authors:  Zhuo Chai; You-Min Zhu; Pei-Jun Yang; Shaoyin Wang; Shaowu Wang; Zhen Liu; Gaosheng Yang
Journal:  J Am Chem Soc       Date:  2015-08-04       Impact factor: 15.419

10.  Heterobimetallic nitride complexes from terminal chromium(V) nitride complexes: hyperfine coupling increases with distance.

Authors:  Jesper Bendix; Christian Anthon; Magnus Schau-Magnussen; Theis Brock-Nannestad; Johan Vibenholt; Muniza Rehman; Stephan P A Sauer
Journal:  Angew Chem Int Ed Engl       Date:  2011-04-06       Impact factor: 15.336
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  3 in total

1.  A Chiral Macrocyclic Tetra-N-Heterocyclic Carbene Yields an "All Carbene" Iron Alkylidene Complex.

Authors:  Joseph F DeJesus; David M Jenkins
Journal:  Chemistry       Date:  2020-01-22       Impact factor: 5.236

2.  Synthesis of Chromium(II) Complexes with Chelating Bis(alkoxide) Ligand and Their Reactions with Organoazides and Diazoalkanes.

Authors:  Sudheer S Kurup; Richard J Staples; Richard L Lord; Stanislav Groysman
Journal:  Molecules       Date:  2020-01-09       Impact factor: 4.411

3.  Toward asymmetric aziridination with an iron complex supported by a D2-symmetric tetra-NHC.

Authors:  Kevin M Blatchford; Carson J Mize; Sharani Roy; David M Jenkins
Journal:  Dalton Trans       Date:  2022-04-20       Impact factor: 4.569
  3 in total

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