Literature DB >> 25265968

Probing the role of an Fe(IV) tetrazene in catalytic aziridination.

S Alan Cramer1, Raúl Hernández Sánchez, Desirae F Brakhage, David M Jenkins.   

Abstract

An iron(IV) tetrazene complex has been synthesized that is an important addition to a previously proposed catalytic aziridination cycle. It provides two key insights about the aziridination: an iron(IV) imide is formed and this imide can bind an additional ligand in the cis position.

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Year:  2014        PMID： 25265968     DOI： 10.1039/c4cc05124f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  7 in total

1.  Styrene Aziridination by Iron(IV) Nitrides.

Authors:  Salvador B Muñoz; Wei-Tsung Lee; Diane A Dickie; Jeremiah J Scepaniak; Deepak Subedi; Maren Pink; Michael D Johnson; Jeremy M Smith
Journal:  Angew Chem Int Ed Engl       Date:  2015-07-15       Impact factor: 15.336

2.  Elucidation of the Reaction Mechanism of C2 + N1 Aziridination from Tetracarbene Iron Catalysts.

Authors:  Sara B Isbill; Preeti P Chandrachud; Jesse L Kern; David M Jenkins; Sharani Roy
Journal:  ACS Catal       Date:  2019-05-31       Impact factor: 13.084

3.  Unprecedented Five-Coordinate Iron(IV) Imides Generate Divergent Spin States Based on the Imide R-Groups.

Authors:  Markus R Anneser; Gaya R Elpitiya; Jacob Townsend; Elizabeth J Johnson; Xian B Powers; Joseph F DeJesus; Konstantinos D Vogiatzis; David M Jenkins
Journal:  Angew Chem Int Ed Engl       Date:  2019-05-07       Impact factor: 15.336

4.  Catalytic aziridination with alcoholic substrates via a chromium tetracarbene catalyst.

Authors:  C Luke Keller; Jesse L Kern; Bradley D Terry; Sharani Roy; David M Jenkins
Journal:  Chem Commun (Camb)       Date:  2018-01-04       Impact factor: 6.222

5.  Rh2(II)-Catalyzed Intermolecular N-Aryl Aziridination of Olefins Using Nonactivated N Atom Precursors.

Authors:  Tianning Deng; Wrickban Mazumdar; Yuki Yoshinaga; Pooja B Patel; Dana Malo; Tala Malo; Donald J Wink; Tom G Driver
Journal:  J Am Chem Soc       Date:  2021-11-08       Impact factor: 15.419

6.  A Chiral Macrocyclic Tetra-N-Heterocyclic Carbene Yields an "All Carbene" Iron Alkylidene Complex.

Authors:  Joseph F DeJesus; David M Jenkins
Journal:  Chemistry       Date:  2020-01-22       Impact factor: 5.236

7.  Enantioselective C-H Amination Catalyzed by Nickel Iminyl Complexes Supported by Anionic Bisoxazoline (BOX) Ligands.

Authors:  Yuyang Dong; Colton J Lund; Gerard J Porter; Ryan M Clarke; Shao-Liang Zheng; Thomas R Cundari; Theodore A Betley
Journal:  J Am Chem Soc       Date:  2021-01-04       Impact factor: 16.383
  7 in total

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