Eizi Hirota1. 1. The Graduate University for Advanced Studies.
Abstract
The double minimum potential (DMP), which Hund assumed to explain the quantum-mechanical stability of enantiomers, was discussed, by citing three typical examples of DMP: inversion, internal rotation, and puckering. They expanded the classical scope of chirality, as defined by Kelvin, and indicated that a new bridge could be formed between the three low-frequency DMP modes and the asymmetric syntheses of chiral molecules.
The double minimum potential (class="Chemical">DMP), which Huclass="Chemical">nd assumed to explaiclass="Chemical">n the quaclass="Chemical">ntum-mechaclass="Chemical">nical stability of eclass="Chemical">naclass="Chemical">ntiomers, was discussed, by citiclass="Chemical">ng three typical examples of class="Chemical">n class="Chemical">DMP: inversion, internal rotation, and puckering. They expanded the classical scope of chirality, as defined by Kelvin, and indicated that a new bridge could be formed between the three low-frequency DMP modes and the asymmetric syntheses of chiral molecules.
Authors: Yoshiyuki Kawashima; Tsuyoshi Usami; Nobukimi Ohashi; Richard D Suenram; Jon T Hougen; Eizi Hirota Journal: Acc Chem Res Date: 2006-03 Impact factor: 22.384
Authors: V Alvin Shubert; David Schmitz; David Patterson; John M Doyle; Melanie Schnell Journal: Angew Chem Int Ed Engl Date: 2013-12-06 Impact factor: 15.336
Authors: V Alvin Shubert; David Schmitz; Chris Medcraft; Anna Krin; David Patterson; John M Doyle; Melanie Schnell Journal: J Chem Phys Date: 2015-06-07 Impact factor: 3.488