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Literature DB >> 22450539

Triple resonance for a three-level system of a chiral molecule.

Abstract

A new spectroscopic method of triple resonance is proposed for studying chirality of a molecule of C₁ symmetry. Each enantiomer of such a molecule is of mixed parity and thus exhibits all three a-, b-, and c-types of rotational spectra. The present study concludes, by using time-dependent perturbation theory, that the transition probability between two of the three rotational levels under triple resonance differs for different enantiomer. This result can thus be of some significance for enantiomer differentiation.

Entities: Chemical Disease Gene Species

Mesh：

Year: 2012 PMID： 22450539 PMCID： PMC3365249 DOI： 10.2183/pjab.88.120

Source DB: PubMed Journal: Proc Jpn Acad Ser B Phys Biol Sci ISSN： 0386-2208 Impact factor: 3.493

10 in total

1. Internal Rotation of the Hydroxyl Group in Isopropanol and the Chirality of the Gauche Form: Fourier Transform Microwave Spectroscopy of (CH(3))(2)CHOD.

Authors: Eizi Hirota; Yoshiyuki Kawashima
Journal: J Mol Spectrosc Date: 2001-06 Impact factor: 1.507

Review 2. How important is parity violation for molecular and biomolecular chirality?

Authors: Martin Quack
Journal: Angew Chem Int Ed Engl Date: 2002-12-16 Impact factor: 15.336

3. High-resolution spectroscopy of induced chiral dimers: a study of the dimers of ethanol by Fourier transform microwave spectroscopy.

Authors: J Paul I Hearn; Rachel V Cobley; Brian J Howard
Journal: J Chem Phys Date: 2005-10-01 Impact factor: 3.488

4. Chiral self-recognition: direct spectroscopic detection of the homochiral and heterochiral dimers of propylene oxide in the gas phase.

Authors: Zheng Su; Nicole Borho; Yunjie Xu
Journal: J Am Chem Soc Date: 2006-12-27 Impact factor: 15.419

5. Lock-and-key principle on a microscopic scale: the case of the propylene oxide...ethanol complex.

Authors: Nicole Borho; Yunjie Xu
Journal: Angew Chem Int Ed Engl Date: 2007 Impact factor: 15.336

6. Hund's paradox and the collisional stabilization of chiral molecules.

Authors: Johannes Trost; Klaus Hornberger
Journal: Phys Rev Lett Date: 2009-07-10 Impact factor: 9.161

7. Chiral recognition between alpha-hydroxylesters: a double-resonance IR/UV study of the complexes of methyl mandelate with methyl glycolate and methyl lactate.

Authors: Katia Le Barbu-Debus; Michel Broquier; Ahmed Mahjoub; Anne Zehnacker-Rentien
Journal: J Phys Chem A Date: 2008-09-09 Impact factor: 2.781

8. Molecular recognition of chiral conformers: a rotational study of the dimers of glycidol.

Authors: Assimo Maris; Barbara M Giuliano; Daria Bonazzi; Walther Caminati
Journal: J Am Chem Soc Date: 2008-09-26 Impact factor: 15.419

9. Structures, inversion barriers, and parity violation effects in chiral SeOXY molecules (X,Y = H, F, Cl, Br, or I).

Authors: Detlev Figgen; Peter Schwerdtfeger
Journal: J Chem Phys Date: 2009-02-07 Impact factor: 3.488

10. Molecular recognition in 1 : 1 hydrogen-bonded complexes of oxirane and trans-2,3-dimethyloxirane with ethanol: a rotational spectroscopic and ab initio study.

Authors: Nicole Borho; Yunjie Xu
Journal: Phys Chem Chem Phys Date: 2007-06-25 Impact factor: 3.676