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Literature DB >> 29211456

Ultrastable Gold Nanoparticles Modified by Bidentate N-Heterocyclic Carbene Ligands.

Renee W Y Man¹, Chien-Hung Li², Michael W A MacLean², Olena V Zenkina², Matthew T Zamora², Lisa N Saunders², Alexander Rousina-Webb², Masakazu Nambo¹, Cathleen M Crudden^2,1.

Abstract

Highly stable gold nanoparticles (Au NPs) functionalized by bidentate N-heterocyclic carbene (NHC) ligands have been synthesized by top-down and bottom-up approaches. A detailed study of the effect of alkylation, denticity, and method of synthesis has led to the production of NHC-stabilized nanoparticles with higher thermal stability than bi- and tridentate thiol-protected Au NPs and than monodentate NHC-stabilized NPs. Importantly, bidentate NHC-protected NPs also displayed unprecedented stability to external thiol, which has been an unsolved problem to date with all nanoparticles. Thus, multidentate NHC ligands are an important, and as yet unrecognized, step forward for the preparation of high stability nanomaterials.

Entities: Chemical Disease

Year: 2018 PMID： 29211456 DOI： 10.1021/jacs.7b08516

Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419

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Cited

13 in total

1. N-heterocyclic carbene-stabilized metal nanoparticles within porous organic cages for catalytic application.

Authors: Tong Liu; Sha Bai; Le Zhang; F Ekkehardt Hahn; Ying-Feng Han
Journal: Natl Sci Rev Date: 2022-04-05 Impact factor: 23.178

2. Hemoglobin-driven iron-directed assembly of gold nanoparticles.

Authors: Jacquelyn G Egan; Nicole Drossis; Iraklii I Ebralidze; Holly M Fruehwald; Nadia O Laschuk; Jade Poisson; Hendrick W de Haan; Olena V Zenkina
Journal: RSC Adv Date: 2018-04-26 Impact factor: 4.036

3. An Organometallic Strategy for Assembling Atomically Precise Hybrid Nanomaterials.

Authors: Julia M Stauber; Elaine A Qian; Yanxiao Han; Arnold L Rheingold; Petr Král; Daishi Fujita; Alexander M Spokoyny
Journal: J Am Chem Soc Date: 2019-12-18 Impact factor: 15.419

4. NHC-Stabilized Au₁₀ Nanoclusters and Their Conversion to Au₂₅ Nanoclusters.

Authors: Paul A Lummis; Kimberly M Osten; Tetyana I Levchenko; Maryam Sabooni Asre Hazer; Sami Malola; Bryan Owens-Baird; Alex J Veinot; Emily L Albright; Gabriele Schatte; Shinjiro Takano; Kirill Kovnir; Kevin G Stamplecoskie; Tatsuya Tsukuda; Hannu Häkkinen; Masakazu Nambo; Cathleen M Crudden
Journal: JACS Au Date: 2022-04-06

Ultrastable Gold Nanoparticles Modified by Bidentate N-Heterocyclic Carbene Ligands.

1. N-heterocyclic carbene-stabilized metal nanoparticles within porous organic cages for catalytic application.

2. Hemoglobin-driven iron-directed assembly of gold nanoparticles.

3. An Organometallic Strategy for Assembling Atomically Precise Hybrid Nanomaterials.

4. NHC-Stabilized Au₁₀ Nanoclusters and Their Conversion to Au₂₅ Nanoclusters.

5. Spectroscopic Evidence for a Covalent Sigma Au-C Bond on Au Surfaces Using ¹³C Isotope Labeling.

6. N-Heterocyclic Carbene Ligand Stability on Gold Nanoparticles in Biological Media.

Review 7. Nanoparticles Targeting Macrophages as Potential Clinical Therapeutic Agents Against Cancer and Inflammation.

Review 8. Prospects of Coupled Organic-Inorganic Nanostructures for Charge and Energy Transfer Applications.

9. Synthetically Versatile Nitrogen Acyclic Carbene Stabilized Gold Nanoparticles.

10. Self-assembly of N-heterocyclic carbenes on Au(111).