Nanotechnology-based recent approaches for sensing and remediation of pesticides.

Pesticides are meant to control and destroy the pests and weeds. They are classified into different categories on the basis their origin and type of pest they target. Chemical pesticides such as insecticides, herbicides and fungicides are commonly used in agricultural fields. However, the excessive use of these agrochemicals have adverse effects on environment such as reduced population of insect pollinators, threat to endangered species and habitat of birds. Upon consumption; chemical pesticides also cause various health issues such as skin, eye and nervous system related problems and cancer upon prolonged exposure. Various techniques in the past have been developed on the basis of surface adsorption, membrane filtration and biological degradation to reduce the content of pesticides. However, slow response, less specificity and sensitivity are some of the drawbacks of such techniques. In recent times, Nanotechnology has emerged as a helping tool for the sensing and remediation of pesticides. This review focuses on the use of this technology for the detection, degradation and removal of pesticides. Nanomaterials have been classified into nanoparticles, nanotubes and nanocomposites that are commonly used for detection, degradation and removal of pesticides. The review also focuses on the chemistry behind the sensing and remediation of pesticides using nanomaterials. Different types of nanoparticles, viz. metal nanoparticles, bimetallic nanoparticles and metal oxide nanoparticles; nanotubes such as carbon nanotubes and halloysite nanotubes have been used for the detection, degradation and removal of pesticides. Further, various enzyme-based biosensors for detection of pesticides have also been summarized.