Hydrogen Electrooxidation in Ionic Liquids Catalyzed by the NTf2 Radical.

Hydrogen electrooxidation via a "hydrogen abstraction" mechanism in an aprotic ionic liquid 1-butyl-1-methylpyrrolidinium bis-(trifluoromethylsulfonyl) [Bmpy][NTf2] under anaerobic conditions was investigated using cyclic voltammetry and density functional theory (DFT). It is found that a platinum bound NTf2 radical (NTf2•) formed by the oxidation of NTf2- at anodic potential can catalyze the oxidation of hydrogen and enhance its reaction rate. Both experimental and theoretical studies (DFT) have supported a mechanism involving a NTf2• radical intermediate that catalyzes the hydrogen redox processes.