Literature DB >> 29038817

Silver-induced self-immolative Cl-F exchange fluorination of arylsulfur chlorotetrafluorides: synthesis of arylsulfur pentafluorides.

Benqiang Cui1, Shichong Jia, Etsuko Tokunaga, Norimichi Saito, Norio Shibata.   

Abstract

A novel strategy for the synthesis of arylsulfur pentafluorides by silver carbonate-induced Cl-F exchange fluorination of arylsulfur chlorotetrafluorides is reported. This fluorination does not require any exogenous fluoride sources. Rather, the reaction proceeds via the self-immolation of the substrate Ar-SF4Cl.

Entities:  

Year:  2017        PMID： 29038817     DOI： 10.1039/c7cc07222h

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  5 in total

1.  Studies of Halogen Bonding Induced by Pentafluorosulfanyl Aryl Iodides: A Potential Group of Halogen Bond Donors in a Rational Drug Design.

Authors:  Yuji Sumii; Kenta Sasaki; Seiji Tsuzuki; Norio Shibata
Journal:  Molecules       Date:  2019-10-07       Impact factor: 4.411

2.  The Supramolecular Structural Chemistry of Pentafluorosulfanyl and Tetrafluorosulfanylene Compounds.

Authors:  Phil Liebing; Cody Ross Pitts; Marc Reimann; Nils Trapp; David Rombach; Dustin Bornemann; Martin Kaupp; Antonio Togni
Journal:  Chemistry       Date:  2021-03-03       Impact factor: 5.236

Review 3.  (Hetero)aryl-SVI Fluorides: Synthetic Development and Opportunities.

Authors:  Marc Magre; Shengyang Ni; Josep Cornella
Journal:  Angew Chem Int Ed Engl       Date:  2022-04-27       Impact factor: 16.823

Review 4.  Oxidative Fluorination of Heteroatoms Enabled by Trichloroisocyanuric Acid and Potassium Fluoride.

Authors:  Yannick Kraemer; Emily Nicole Bergman; Antonio Togni; Cody Ross Pitts
Journal:  Angew Chem Int Ed Engl       Date:  2022-06-21       Impact factor: 16.823

5.  An eccentric rod-like linear connection of two heterocycles: synthesis of pyridine trans-tetrafluoro-λ6-sulfanyl triazoles.

Authors:  Prajwalita Das; Kiyoteru Niina; Tomoya Hiromura; Etsuko Tokunaga; Norimichi Saito; Norio Shibata
Journal:  Chem Sci       Date:  2018-05-14       Impact factor: 9.825
  5 in total

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