Literature DB >> 29019479

Facile insertion of a cyclic alkyl(amino) carbene carbon into the B-B bond of diboron(4) reagents.

Antonius F Eichhorn1, Laura Kuehn, Todd B Marder, Udo Radius.   

Abstract

We report herein the room temperature insertion of the carbene carbon atom of the cyclic (alkyl)(amino) carbene cAACMe into the B-B single bonds of the diboron(4) compounds B2pin2, B2cat2, B2neop2, and B2eg2 (pin = pinacolato, cat = catecholato, neop = neopentylglycolato, eg = ethyleneglycolato).

Entities:  

Year:  2017        PMID： 29019479     DOI： 10.1039/c7cc06302d

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  3 in total

Review 1.  Recent Advances in the Domain of Cyclic (Alkyl)(Amino) Carbenes.

Authors:  Saroj Kumar Kushvaha; Ankush Mishra; Herbert W Roesky; Kartik Chandra Mondal
Journal:  Chem Asian J       Date:  2022-02-26

2.  B-B Cleavage and Ring-Expansion of a 1,4,2,3-Diazadiborinine with N-Heterocyclic Carbenes.

Authors:  Torsten Thiess; Soren K Mellerup; Holger Braunschweig
Journal:  Chemistry       Date:  2019-09-19       Impact factor: 5.236

3.  Selective Boryl-Anion Migration in a Vinyl sp2 -sp3 Diborane Induced by Soft Borane Lewis Acids.

Authors:  Valerio Fasano; Jessica Cid; Richard J Procter; Emily Ross; Michael J Ingleson
Journal:  Angew Chem Int Ed Engl       Date:  2018-09-10       Impact factor: 15.336
  3 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.