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Literature DB >> 28885017

Parameterization of Acyclic Diaminocarbene Ligands Applied to a Gold(I)-Catalyzed Enantioselective Tandem Rearrangement/Cyclization.

Zachary L Niemeyer¹, Suresh Pindi², Dimitri A Khrakovsky², Christian N Kuzniewski², Cynthia M Hong², Leo A Joyce³, Matthew S Sigman¹, F Dean Toste².

Abstract

Computed descriptors for acyclic diaminocarbene ligands are developed in the context of a gold catalyzed enantioselective tandem [3,3]-sigmatropic rearrangement-[2+2]-cyclization. Surrogate structures enable the rapid identification of parameters that reveal mechanistic characteristics. The observed selectivity trends are validated in a robust multivariate analysis facilitating the development of a highly enantioselective process.

Entities: Chemical Disease Gene

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Year: 2017 PMID： 28885017 PMCID： PMC5903265 DOI： 10.1021/jacs.7b08791

Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419

31 in total

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