| Literature DB >> 28872885 |
Ajay Kumar Sharma1, Mrutyunjay Nair1, Preeti Chauhan1, Kavya Gupta2, Deepak K Saini2, Harinath Chakrapani1.
Abstract
Generation of hydrogen sulfide (H2S) is challenging and few methods are capable of localized delivery of this gas. Here, a boron dipyrromethene-based carbamothioate (BDP-H2S) that is uncaged by visible light of 470 nm to generate carbonyl sulfide (COS), which is rapidly hydrolyzed to H2S in the presence of carbonic anhydrase, a widely prevalent enzyme, is reported.Entities:
Year: 2017 PMID： 28872885 DOI： 10.1021/acs.orglett.7b02259
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005