Determination of total mercury in aluminium industrial zones and soil contaminated with red mud.

This study investigated total mercury contents in areas impacted by aluminium plants in Tajikistan and Slovakia and in one area flooded with red mud in Hungary. We present the first determination of total mercury contents in the near-top soil (0-10 and 10-20 cm) in Tajikistan and the first comparative investigation of Tajikistan-Slovakia-Hungary. The Tajik Aluminium Company (TALCO) is one of the leading producers of primary aluminium in Central Asia. In the past 30 years, the plant has been producing large volumes of industrial waste, resulting in negative impacts on soil, groundwater and air quality of the surrounding region. Mercury concentrations were significant in Slovakia and Hungary, 6 years after the flooding. In studied areas in Slovakia and Hungary, concentrations of total mercury exceeded the threshold limit value (TLV = 0.5 mg Hg kg-1). However, in Tajikistan, values were below the TLV (0.006-0.074 mg kg-1) and did not significantly vary between depths. Total Hg in Slovakia ranged from 0.057 to 0.668 mg kg-1 and in Hungary from 0.029 to 1.275 mg kg-1. However, in the plots near to the red mud reservoir and the flooded area, Hg concentrations were higher in the upper layers than in the lower ones.