Literature DB >> 28620693

Comparative studies of reaction of cobalamin (II) and cobinamide (II) with sulfur dioxide.

Ilia A Dereven'kov1, Pavel A Ivlev1, Cristina Bischin2, Denis S Salnikov3, Radu Silaghi-Dumitrescu2, Sergei V Makarov1, Oscar I Koifman1.   

Abstract

The kinetics of reactions of cobalamin (II) and cobinamide (II) with sulfur dioxide was studied by UV-visible (UV-vis) spectroscopy. Reaction results in oxidation of Co(II) center and involves two aquated SO2 moieties. The final product is suggested to be complex Co(III)-S2O 4•- . The absence of corrin ring modifications during the reactions was proved.

Entities:  

Keywords:  Cobalamin; Cobinamide; Kinetics; Redox reactions; Sulfur dioxide

Mesh:

Substances:

Year:  2017        PMID: 28620693     DOI: 10.1007/s00775-017-1474-z

Source DB:  PubMed          Journal:  J Biol Inorg Chem        ISSN: 0949-8257            Impact factor:   3.358


  30 in total

Review 1.  The relationship between structure and function for the sulfite reductases.

Authors:  B R Crane; E D Getzoff
Journal:  Curr Opin Struct Biol       Date:  1996-12       Impact factor: 6.809

2.  Electromerism and linkage isomerism in biologically-relevant Fe-SO complexes.

Authors:  Mihai Surducan; Dora Lup; Alexandru Lupan; Sergei V Makarov; Radu Silaghi-Dumitrescu
Journal:  J Inorg Biochem       Date:  2012-09-21       Impact factor: 4.155

3.  Activation of SO2 and CO2 by trivalent uranium leading to sulfite/dithionite and carbonate/oxalate complexes.

Authors:  Anna-Corina Schmidt; Frank W Heinemann; Christos E Kefalidis; Laurent Maron; Peter W Roesky; Karsten Meyer
Journal:  Chemistry       Date:  2014-08-21       Impact factor: 5.236

4.  Mechanistic studies on the reaction between cob(II)alamin and peroxynitrite: evidence for a dual role for cob(II)alamin as a scavenger of peroxynitrous acid and nitrogen dioxide.

Authors:  Riya Mukherjee; Nicola E Brasch
Journal:  Chemistry       Date:  2011-09-16       Impact factor: 5.236

5.  Quantitative analysis by liquid chromatography-tandem mass spectrometry of glycidamide using the cob(I)alamin trapping method: validation and application to in vitro metabolism of acrylamide.

Authors:  Hitesh V Motwani; Margareta Törnqvist
Journal:  J Chromatogr A       Date:  2011-05-13       Impact factor: 4.759

6.  Cob(I)alamin reacts with sucralose to afford an alkylcobalamin: relevance to in vivo cobalamin and sucralose interaction.

Authors:  Hitesh V Motwani; Shiran Qiu; Bernard T Golding; Henrik Kylin; Margareta Törnqvist
Journal:  Food Chem Toxicol       Date:  2010-12-02       Impact factor: 6.023

7.  Nitric oxide scavenging by the cobalamin precursor cobinamide.

Authors:  Kate E Broderick; Veena Singh; Shunhui Zhuang; Amanpreet Kambo; Jeffrey C Chen; Vijay S Sharma; Renate B Pilz; Gerry R Boss
Journal:  J Biol Chem       Date:  2005-01-04       Impact factor: 5.157

8.  A simple, convenient method to synthesize cobalamins: synthesis of homocysteinylcobalamin, N-acetylcysteinylcobalamin, 2-N-acetylamino-2-carbomethoxyethanethiolatocobalamin, sulfitocobalamin and nitrocobalamin.

Authors:  Edward Suarez-Moreira; Luciana Hannibal; Clyde A Smith; Roberto A Chavez; Donald W Jacobsen; Nicola E Brasch
Journal:  Dalton Trans       Date:  2006-09-21       Impact factor: 4.390

9.  Vitamin B(12) and redox homeostasis: cob(II)alamin reacts with superoxide at rates approaching superoxide dismutase (SOD).

Authors:  Edward Suarez-Moreira; June Yun; Catherine S Birch; John H H Williams; Andrew McCaddon; Nicola E Brasch
Journal:  J Am Chem Soc       Date:  2009-10-28       Impact factor: 15.419

10.  Sulfite reductase structure at 1.6 A: evolution and catalysis for reduction of inorganic anions.

Authors:  B R Crane; L M Siegel; E D Getzoff
Journal:  Science       Date:  1995-10-06       Impact factor: 47.728

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