| Literature DB >> 28620693 |
Ilia A Dereven'kov1, Pavel A Ivlev1, Cristina Bischin2, Denis S Salnikov3, Radu Silaghi-Dumitrescu2, Sergei V Makarov1, Oscar I Koifman1.
Abstract
The kinetics of reactions of cobalamin (II) and cobinamide (II) with sulfur dioxide was studied by UV-visible (UV-vis) spectroscopy. Reaction results in oxidation of Co(II) center and involves two aquated SO2 moieties. The final product is suggested to be complex Co(III)-S2O 4•- . The absence of corrin ring modifications during the reactions was proved.Entities:
Keywords: Cobalamin; Cobinamide; Kinetics; Redox reactions; Sulfur dioxide
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Year: 2017 PMID: 28620693 DOI: 10.1007/s00775-017-1474-z
Source DB: PubMed Journal: J Biol Inorg Chem ISSN: 0949-8257 Impact factor: 3.358