| Literature DB >> 28481107 |
Shino Tooriyama1, Yuji Mimori1, Yuqiu Wu1, Noriyuki Kogure1, Mariko Kitajima1, Hiromitsu Takayama1.
Abstract
The first asymmetric total synthesis of andranginine (1) via an asymmetric Morita-Baylis-Hillman reaction and a diastereoselective intramolecular Diels-Alder reaction has revealed that natural andranginine (1) isolated from Kopsia arborea existed as a scalemic mixture and contained predominantly the (16R,21S) form rather than the (16S,21R) form.Entities:
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Year: 2017 PMID： 28481107 DOI： 10.1021/acs.orglett.7b01076
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005