Literature DB >> 28426933

Triggering Assembly and Disassembly of a Supramolecular Cage.

Carlo Bravin1, Elena Badetti1, Francesca A Scaramuzzo1, Giulia Licini1, Cristiano Zonta1.   

Abstract

A novel supramolecular cage built from the self-assembly of tris(2-pyridylmethyl)amine zinc complexes through imine condensation chemistry is reported. The cage recognition properties over a variety of structurally related guests, together with the kinetic study of the template assembly and disassembly, have been investigated in detail. This knowledge has been used to selectively modulate the rate of both assembly and disassembly processes. In particular, a novel disassembly method induced by strain release of the guest has been developed.

Entities:  

Year:  2017        PMID： 28426933     DOI： 10.1021/jacs.7b02341

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  5 in total

1.  Diasteroselective multi-component assemblies from dynamic covalent imine condensation and metal-coordination chemistry: mechanism and narcissistic stereochemistry self-sorting.

Authors:  Elena Badetti; Nadia Alessandra Carmo Dos Santos; Francesca A Scaramuzzo; Carlo Bravin; Klaus Wurst; Giulia Licini; Cristiano Zonta
Journal:  RSC Adv       Date:  2018-05-29       Impact factor: 4.036

2.  Chiroptical Enhancement of Chiral Dicarboxylic Acids from Confinement in a Stereodynamic Supramolecular Cage.

Authors:  Federico Begato; Roberto Penasa; Giulia Licini; Cristiano Zonta
Journal:  ACS Sens       Date:  2022-04-26       Impact factor: 9.618

3.  Waterproof architectures through subcomponent self-assembly.

Authors:  Edmundo G Percástegui; Jesús Mosquera; Tanya K Ronson; Alex J Plajer; Marion Kieffer; Jonathan R Nitschke
Journal:  Chem Sci       Date:  2018-12-12       Impact factor: 9.825

4.  Quantified structural speciation in self-sorted CoII6L4 cage systems.

Authors:  Felix J Rizzuto; Marion Kieffer; Jonathan R Nitschke
Journal:  Chem Sci       Date:  2018-01-10       Impact factor: 9.825

5.  Organic Polyradicals as Redox Mediators: Effect of Intramolecular Radical Interactions on Their Efficiency.

Authors:  Elena Badetti; Vega Lloveras; Emanuele Amadio; Rosalia Di Lorenzo; Mara Olivares-Marín; Alvaro Y Tesio; Songbai Zhang; Fangfang Pan; Kari Rissanen; Jaume Veciana; Dino Tonti; Jose Vidal-Gancedo; Cristiano Zonta; Giulia Licini
Journal:  ACS Appl Mater Interfaces       Date:  2020-09-29       Impact factor: 9.229
  5 in total

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