| Literature DB >> 28240405 |
Ryota Sakamoto1,2, Toshiki Yagi1, Ken Hoshiko1, Shinpei Kusaka1, Ryota Matsuoka1, Hiroaki Maeda1, Zheng Liu3,4, Qian Liu5,6,7, Wai-Yeung Wong5,6,8, Hiroshi Nishihara1.
Abstract
New bis(dipyrrinato)zinc(II) complex micro- and nanosheets containing zinc(II) porphyrin (N2) are synthesized. A liquid/liquid interface method between dipyrrin porphyrin ligand L2 and zinc acetate produces N2 with a large domain size. N2 can be layered quantitatively onto a flat substrate by a modified Langmuir-Schäfer method. N2 deposited on a SnO2 electrode functions as a photoanode for a photoelectric conversion system. The photoresponse of N2 covers the whole visible wavelength range (400-650 nm), with a maximum quantum efficiency of more than twice that of a bis(dipyrrinato)zinc(II) complex nanosheet without porphyrin.Entities:
Keywords: metal-organic frameworks (MOFs); nanosheets; photovoltaics; porphyrins; zinc
Year: 2017 PMID: 28240405 DOI: 10.1002/anie.201611785
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN: 1433-7851 Impact factor: 15.336