Literature DB >> 28160366

Mapping-Out Catalytic Processes in a Metal-Organic Framework with Single-Crystal X-ray Crystallography.

Alexandre Burgun1, Campbell J Coghlan1, David M Huang1, Wenqian Chen2, Satoshi Horike2, Susumu Kitagawa2, Jason F Alvino1, Gregory F Metha1, Christopher J Sumby1, Christian J Doonan1.   

Abstract

Single-crystal X-ray crystallography is employed to characterize the reaction species of a full catalytic carbonylation cycle within a MnII -based metal-organic framework (MOF) material. The structural insights explain why the Rh metalated MOF is catalytically competent toward the carbonylation of MeBr but only affords stoichiometric turn-over in the case of MeI. This work highlights the capability of MOFs to act as platform materials for studying single-site catalysis in heterogeneous systems.
© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  MOFs; carbonylation; heterogeneous catalysis; rhodium complexes; structure elucidation

Year:  2017        PMID： 28160366     DOI： 10.1002/anie.201611254

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  7 in total

1.  Heterogeneous Epoxide Carbonylation by Cooperative Ion-Pair Catalysis in Co(CO)4--Incorporated Cr-MIL-101.

Authors:  Hoyoung D Park; Mircea Dincă; Yuriy Román-Leshkov
Journal:  ACS Cent Sci       Date:  2017-03-21       Impact factor: 14.553

2.  Approaches to the Synthesis of Dicarboxylic Derivatives of Bis(pyrazol-1-yl)alkanes.

Authors:  Nikita P Burlutskiy; Andrei S Potapov
Journal:  Molecules       Date:  2021-01-14       Impact factor: 4.411

3.  Metal-Organic Frameworks as Unique Platforms to Gain Insight of σ-Hole Interactions for the Removal of Organic Dyes from Aquatic Ecosystems.

Authors:  Cristina Negro; Paula Escamilla; Rosaria Bruno; Jesus Ferrando-Soria; Donatella Armentano; Emilio Pardo
Journal:  Chemistry       Date:  2022-03-24       Impact factor: 5.020

4.  Highly Efficient MOF-Driven Silver Subnanometer Clusters for the Catalytic Buchner Ring Expansion Reaction.

Authors:  Estefanía Tiburcio; Yongkun Zheng; Marta Mon; Nuria Martín; Jesús Ferrando Soria; Donatella Armentano; Antonio Leyva Pérez; Emilio Pardo
Journal:  Inorg Chem       Date:  2022-07-21       Impact factor: 5.436

5.  Encapsulation of Crabtree's Catalyst in Sulfonated MIL-101(Cr): Enhancement of Stability and Selectivity between Competing Reaction Pathways by the MOF Chemical Microenvironment.

Authors:  Alexios Grigoropoulos; Alasdair I McKay; Alexandros P Katsoulidis; Robert P Davies; Anthony Haynes; Lee Brammer; Jianliang Xiao; Andrew S Weller; Matthew J Rosseinsky
Journal:  Angew Chem Int Ed Engl       Date:  2018-03-22       Impact factor: 15.336

6.  Co₂ and Co₃ Mixed Cluster Secondary Building Unit Approach toward a Three-Dimensional Metal-Organic Framework with Permanent Porosity.

Authors:  Meng-Yao Chao; Wen-Hua Zhang; Jian-Ping Lang
Journal:  Molecules       Date:  2018-03-25       Impact factor: 4.411

7.  Solid-State Molecular Organometallic Catalysis in Gas/Solid Flow (Flow-SMOM) as Demonstrated by Efficient Room Temperature and Pressure 1-Butene Isomerization.

Authors:  Antonio J Martínez-Martínez; Cameron G Royle; Samantha K Furfari; Kongkiat Suriye; Andrew S Weller
Journal:  ACS Catal       Date:  2020-01-06       Impact factor: 13.084
  7 in total

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