| Literature DB >> 27995460 |
Şükriye Nihan Karuk Elmas1, Furkan Ozen2, Kenan Koran2, Ibrahim Yilmaz3,3, Ahmet Orhan Gorgulu2, Serkan Erdemir4.
Abstract
Solvent free synthesis of 6,7-dihydroxy-3-(3-chlorophenyl) coumarin (CFHC) was designed and obtained by the interaction of 2-(2,4,5-trimethoxyphenyl)-1-(3-chlorophenyl)acrylonitrile with pyridinium hydrochloride in the presence of silica gel by using microwave irradiation. The characterization of CFHC was confirmed by FT-IR, 1H, 13C, 13C-APT and 2D HETCOR spectroscopy methods. The optical behavior of CFHC towards metal ions was investigated by UV-visible and fluorescence spectroscopy. CFHC showed "on-off" type fluorescence response towards Cu2+ with high selectivity in aqueous solution (CH3CN/H2O, 9/1, v/v). Once binding with Cu2+, CFHC-Cu2+ complex also displayed high selectivity for sulfide, resulting in "off-on" type sensing of sulfide anion. Graphical abstract Visual fluorescence changes upon addition of various metal ions (5.0 eq.) to CFHC in CH3CN/H2O (90:10, v/v) under UV excitation (365 nm).Entities:
Keywords: Copper; Coumarin; Fluorescent; Sensor; Sulfide
Year: 2016 PMID: 27995460 DOI: 10.1007/s10895-016-1972-3
Source DB: PubMed Journal: J Fluoresc ISSN: 1053-0509 Impact factor: 2.217