Literature DB >> 27960331

Transition-Metal-like Behavior of Main Group Elements: Ligand Exchange at a Phosphinidene.

Max M Hansmann1, Guy Bertrand1.   

Abstract

(Phosphino)phosphaketenes (>P-P═C═O) behave as (phosphino)phosphinidene-carbonyl adducts (>P-P←:C═O). CO scrambling was observed using 13C labeled CO, and exchange reactions with phosphines afford the corresponding (phosphino)phosphinidene-phosphine adducts (>P-P←:PR3). The latter react with isonitriles and singlet carbenes giving (phosphino)phosphinidene-isonitrile (>P-P←:CNR) and -carbene adducts (>P-P←:C<). Based on experimental results and DFT calculations, it is shown that these "ligand" exchange reactions occur via an associative mechanism as classically observed with transition metal complexes.

Entities:  

Year:  2016        PMID： 27960331     DOI： 10.1021/jacs.6b11496

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  10 in total

1.  A silicon-carbonyl complex stable at room temperature.

Authors:  Chelladurai Ganesamoorthy; Juliane Schoening; Christoph Wölper; Lijuan Song; Peter R Schreiner; Stephan Schulz
Journal:  Nat Chem       Date:  2020-04-20       Impact factor: 24.427

2.  Quantum chemical study in exploring the role of donor→acceptor interactions in 1,3-bis carbene-stabilized guanidinium cations.

Authors:  Pravin J Wanjari; Tejender Singh; Firdoos Ahmad Sofi; Prasad V Bharatam
Journal:  J Mol Model       Date:  2021-02-17       Impact factor: 1.810

3.  Indirect Access to Carbene Adducts of Bismuth- and Antimony-Substituted Phosphaketene and Their Unusual Thermal Transformation to Dipnictines and [(NHC)2OCP][OCP].

Authors:  Jacob E Walley; Levi S Warring; Erik Kertész; Guocang Wang; Diane A Dickie; Zoltán Benkő; Robert J Gilliard
Journal:  Inorg Chem       Date:  2021-03-09       Impact factor: 5.165

4.  (Phosphanyl)phosphaketenes as building blocks for novel phosphorus heterocycles.

Authors:  Max M Hansmann; David A Ruiz; Liu Leo Liu; Rodolphe Jazzar; Guy Bertrand
Journal:  Chem Sci       Date:  2017-03-08       Impact factor: 9.825

5.  Reactivity enhancement of a diphosphene by reversible N-heterocyclic carbene coordination.

Authors:  Debabrata Dhara; Pankaj Kalita; Subhadip Mondal; Ramakirushnan Suriya Narayanan; Kaustubh R Mote; Volker Huch; Michael Zimmer; Cem B Yildiz; David Scheschkewitz; Vadapalli Chandrasekhar; Anukul Jana
Journal:  Chem Sci       Date:  2018-03-27       Impact factor: 9.825

6.  A Phosphanyl-Phosphagallene that Functions as a Frustrated Lewis Pair.

Authors:  Daniel W N Wilson; Joey Feld; Jose M Goicoechea
Journal:  Angew Chem Int Ed Engl       Date:  2020-09-09       Impact factor: 15.336

7.  Metal-Free N-H Bond Activation by Phospha-Wittig Reagents.

Authors:  Fabian Dankert; Jan-Erik Siewert; Priyanka Gupta; Florian Weigend; Christian Hering-Junghans
Journal:  Angew Chem Int Ed Engl       Date:  2022-07-04       Impact factor: 16.823

8.  Base induced isomerisation of a phosphaethynolato-borane: mechanistic insights into boryl migration and decarbonylation to afford a triplet phosphinidene.

Authors:  Daniel W N Wilson; Mauricio P Franco; William K Myers; John E McGrady; Jose M Goicoechea
Journal:  Chem Sci       Date:  2019-12-02       Impact factor: 9.825

9.  Carbon monoxide insertion at a heavy p-block element: unprecedented formation of a cationic bismuth carbamoyl.

Authors:  Jacqueline Ramler; Jordi Poater; Florian Hirsch; Benedikt Ritschel; Ingo Fischer; F Matthias Bickelhaupt; Crispin Lichtenberg
Journal:  Chem Sci       Date:  2019-02-28       Impact factor: 9.825

10.  Reappraising Schmidpeter's bis(iminophosphoranyl)phosphides: coordination to transition metals and bonding analysis.

Authors:  Adrien T Normand; E Daiann Sosa Carrizo; Corentin Magnoux; Esteban Lobato; Hélène Cattey; Philippe Richard; Stéphane Brandès; Charles H Devillers; Anthony Romieu; Pierre Le Gendre; Paul Fleurat-Lessard
Journal:  Chem Sci       Date:  2020-10-26       Impact factor: 9.825
  10 in total

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