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Literature DB >> 27748111

Preparation of Aryne-Nickel Complexes from ortho-Borylaryl Triflates.

Yuto Sumida¹, Tomoe Sumida¹, Daisuke Hashizume², Takamitsu Hosoya^1,3.

Abstract

A facile method for preparing diverse aryne-nickel complexes from readily synthesized ortho-borylaryl triflates is described. Exploratory synthetic applications, including the synthesis of 1,2-difunctionalized arenes, based on the nucleophilic character of the aryne-nickel complexes are also demonstrated.

Entities: Chemical

Year: 2016 PMID： 27748111 DOI： 10.1021/acs.orglett.6b02831

Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005

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Cited

5 in total

1. Transition-metal-free synthesis of aryl 1-thioglycosides with arynes at room temperature.

Authors: Yao Liu; Xiao-Bing Yu; Xiang-Mei Zhang; Qian Zhong; Li-Hua Liao; Nan Yan
Journal: RSC Adv Date: 2021-08-04 Impact factor: 4.036

2. Extension of the Simmons-Smith reaction to metal-carbynes: efficient synthesis of metallacyclopropenes with σ-aromaticity.

Authors: Fanping Huang; Xuejuan Zheng; Xinlei Lin; Linting Ding; Qingde Zhuo; Ting Bin Wen; Hong Zhang; Haiping Xia
Journal: Chem Sci Date: 2020-09-03 Impact factor: 9.825

Preparation of Aryne-Nickel Complexes from ortho-Borylaryl Triflates.

1. Transition-metal-free synthesis of aryl 1-thioglycosides with arynes at room temperature.

2. Extension of the Simmons-Smith reaction to metal-carbynes: efficient synthesis of metallacyclopropenes with σ-aromaticity.

3. Exploring Possible Surrogates for Kobayashi's Aryne Precursors.

4. Ester dance reaction on the aromatic ring.

5. Facile Synthesis of a Stable Side-on Phosphinyne Complex by Redox Driven Intramolecular Cyclisation.