Literature DB >> 27722278

Metal-free C-H thioarylation of arenes using sulfoxides: a direct, general diaryl sulfide synthesis.

José A Fernández-Salas1, Alexander P Pulis1, David J Procter1.   

Abstract

Metal-free C-H thioarylation of arenes and heteroarenes using methyl sulfoxides constitutes a general protocol for the synthesis of high value diaryl sulfides. The coupling of arenes and heteroarenes with in situ activated sulfoxides is regioselective, uses readily available starting materials, is operationally simple, and tolerates a wide range of functional groups.

Entities:  

Year:  2016        PMID： 27722278     DOI： 10.1039/c6cc07627k

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  8 in total

1.  Bond-Forming and -Breaking Reactions at Sulfur(IV): Sulfoxides, Sulfonium Salts, Sulfur Ylides, and Sulfinate Salts.

Authors:  Daniel Kaiser; Immo Klose; Rik Oost; James Neuhaus; Nuno Maulide
Journal:  Chem Rev       Date:  2019-06-25       Impact factor: 60.622

2.  A template free protocol for fabrication of a Ni(ii)-loaded magnetically separable nanoreactor scaffold for confined synthesis of unsymmetrical diaryl sulfides in water.

Authors:  Gunjan Arora; Manavi Yadav; Rashmi Gaur; Radhika Gupta; Pooja Rana; Priya Yadav; Rakesh Kumar Sharma
Journal:  RSC Adv       Date:  2020-05-21       Impact factor: 4.036

3.  Regioselective synthesis of C3 alkylated and arylated benzothiophenes.

Authors:  Harry J Shrives; José A Fernández-Salas; Christin Hedtke; Alexander P Pulis; David J Procter
Journal:  Nat Commun       Date:  2017-03-20       Impact factor: 14.919

4.  Metal-free O-H/C-H difunctionalization of phenols by o-hydroxyarylsulfonium salts in water.

Authors:  Dengfeng Chen; Qingyuan Feng; Yunqin Yang; Xu-Min Cai; Fei Wang; Shenlin Huang
Journal:  Chem Sci       Date:  2016-11-04       Impact factor: 9.825

5.  Dual vicinal functionalisation of heterocycles via an interrupted Pummerer coupling/[3,3]-sigmatropic rearrangement cascade.

Authors:  Mindaugas Šiaučiulis; Selma Sapmaz; Alexander P Pulis; David J Procter
Journal:  Chem Sci       Date:  2017-11-17       Impact factor: 9.825

6.  Site-Selective Late-Stage Aromatic [18 F]Fluorination via Aryl Sulfonium Salts.

Authors:  Peng Xu; Da Zhao; Florian Berger; Aboubakr Hamad; Jens Rickmeier; Roland Petzold; Mykhailo Kondratiuk; Kostiantyn Bohdan; Tobias Ritter
Journal:  Angew Chem Int Ed Engl       Date:  2019-12-12       Impact factor: 15.336

7.  Synthesis of 6H-Benzo[c]chromene Scaffolds from O-Benzylated Phenols through a C-H Sulfenylation/Radical Cyclization Sequence.

Authors:  Steve Karreman; Simon B H Karnbrock; Sebastian Kolle; Christopher Golz; Manuel Alcarazo
Journal:  Org Lett       Date:  2021-03-01       Impact factor: 6.005

8.  Straightforward Access to Thiocyanates via Dealkylative Cyanation of Sulfoxides.

Authors:  Uroš Todorović; Immo Klose; Nuno Maulide
Journal:  Org Lett       Date:  2021-03-16       Impact factor: 6.005
  8 in total

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