Determination of the volatile fraction of phosphorus flame retardants in cushioning foam of upholstered furniture: towards respiratory exposure assessment.

The purpose of this paper was to highlight potential exposure in indoor air to phosphorus flame retardants (PFRs) due to their use in upholstered furniture. For that, an analytical method of PFRs by headspace coupled to solid-phase micro-extraction (HS-SPME) was developed on cushioning foams in order to determine the PFRs' volatile fraction in the material. Tests on model foams proved the feasibility of the method. The average repeatability (RSD) is 6.3 % and the limits of detection range from 0.33 to 1.29 μg g(-1) of foam, depending on the PFRs. Results showed that some PFRs can actually be emitted in air, leading to a potential risk of exposure by inhalation. The volatile fraction can be high (up to 98 % of the total PFRs amount) and depends on the physicochemical properties of flame retardants, on the textural characteristics of the materials and on the temperature. The methodology developed for cushioning foams could be further applied to other types of materials and can be used to rate them according to their potential releases of phosphorus flame retardants.