Literature DB >> 27560460

Decarbonylative Silylation of Esters by Combined Nickel and Copper Catalysis for the Synthesis of Arylsilanes and Heteroarylsilanes.

Lin Guo1, Adisak Chatupheeraphat1, Magnus Rueping2,3.   

Abstract

An efficient nickel/copper-catalyzed decarbonylative silylation reaction of carboxylic acid esters with silylboranes is described. This reaction provides access to structurally diverse silanes with high efficiency and excellent functional-group tolerance starting from readily available esters.
© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  copper; decarbonylative cross-couplings; esters; nickel; silylation

Year:  2016        PMID： 27560460     DOI： 10.1002/anie.201604696

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  15 in total

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9.  Palladium-Catalyzed Decarbonylative Trifluoromethylation of Acid Fluorides.

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10.  Carbon-11 carboxylation of trialkoxysilane and trimethylsilane derivatives using [11C]CO2.

Authors:  Salvatore Bongarzone; Nicola Raucci; Igor Camargo Fontana; Federico Luzi; Antony D Gee
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