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Literature DB >> 28723158

Pd-Catalyzed Decarbonylative Cross-Couplings of Aroyl Chlorides.

Christian A Malapit¹, Naoko Ichiishi¹, Melanie S Sanford¹.

Abstract

This report describes a method for Pd-catalyzed decarbonylative cross-coupling that enables the conversion of carboxylic acid derivatives to biaryls, aryl amines, aryl ethers, aryl sulfides, aryl boronate esters, and trifluoromethylated arenes. The success of this transformation leverages the Pd0/Brettphos-catalyzed decarbonylative chlorination of aroyl chlorides, which can then participate in diverse cross-coupling reactions in situ using the same Pd catalyst.

Entities: Chemical Species

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Year: 2017 PMID： 28723158 PMCID： PMC5565168 DOI： 10.1021/acs.orglett.7b02024

Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005

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6. Investigation of the Selectivity of the Palladium-Catalyzed Aroylation and Arylation of Stannyl Glycals with Aroyl Chlorides.

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