Literature DB >> 27457353

Transition-Metal-Catalyzed Electrophilic Amination: Application of O-Benzoylhydroxylamines in the Construction of the C-N Bond.

Xu Dong1, Qing Liu1, Yunhui Dong1,2, Hui Liu1,3,2.   

Abstract

Transition-metal-catalyzed electrophilic amination has been developed into a powerful tool for C-N bond construction. So far, O-benzoylhydroxylamines are the most widely used electrophilic aminating reagents. Herein, we summarize the recent advances of O-benzoylhydroxylamines involved in electrophilic amination catalyzed by transition metals. Several pioneering studies and some of the relevant mechanisms are discussed in this review.
© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  O-benzoylhydroxylamines; cross-coupling; electrophilic amination; tertiary amines; transition-metal catalysis

Year:  2016        PMID： 27457353     DOI： 10.1002/chem.201601607

Source DB:  PubMed          Journal:  Chemistry        ISSN： 0947-6539            Impact factor:   5.236


  11 in total

1.  A Modified System for the Synthesis of Enantioenriched N-Arylamines through Copper-Catalyzed Hydroamination.

Authors:  Saki Ichikawa; Shaolin Zhu; Stephen L Buchwald
Journal:  Angew Chem Int Ed Engl       Date:  2018-06-12       Impact factor: 15.336

2.  Non-Deprotonative Primary and Secondary Amination of (Hetero)Arylmetals.

Authors:  Zhe Zhou; Zhiwei Ma; Nicole Erin Behnke; Hongyin Gao; László Kürti
Journal:  J Am Chem Soc       Date:  2016-12-23       Impact factor: 15.419

Review 3.  Cross-Coupling of Heteroatomic Electrophiles.

Authors:  Katerina M Korch; Donald A Watson
Journal:  Chem Rev       Date:  2019-06-11       Impact factor: 60.622

4.  Pd-Catalyzed Alkene Diamination Reactions of Nitrogen Electrophiles: Synthesis of Cyclic Guanidines and Ureas Bearing Dialkylaminomethyl Groups.

Authors:  Luke J Peterson; Janelle K Kirsch; John P Wolfe
Journal:  Org Lett       Date:  2018-06-06       Impact factor: 6.005

5.  A directing group switch in copper-catalyzed electrophilic C-H amination/migratory annulation cascade: divergent access to benzimidazolone/benzimidazole.

Authors:  Hasina Mamataj Begam; Shantanu Nandi; Ranjan Jana
Journal:  Chem Sci       Date:  2022-04-14       Impact factor: 9.969

6.  Traceless Benzylic C-H Amination via Bifunctional N-Aminopyridinium Intermediates.

Authors:  Pritam Roychowdhury; Roberto G Herrera; Hao Tan; David C Powers
Journal:  Angew Chem Int Ed Engl       Date:  2022-05-20       Impact factor: 16.823

7.  Cu-Catalyzed aromatic C-H imidation with N-fluorobenzenesulfonimide: mechanistic details and predictive models.

Authors:  Brandon E Haines; Takahiro Kawakami; Keiko Kuwata; Kei Murakami; Kenichiro Itami; Djamaladdin G Musaev
Journal:  Chem Sci       Date:  2016-10-19       Impact factor: 9.825

8.  Iron-Mediated Electrophilic Amination of Organozinc Halides using Organic Azides.

Authors:  Simon Graßl; Johannes Singer; Paul Knochel
Journal:  Angew Chem Int Ed Engl       Date:  2019-11-19       Impact factor: 15.336

Review 9.  First-Row Late Transition Metals for Catalytic Alkene Hydrofunctionalisation: Recent Advances in C-N, C-O and C-P Bond Formation.

Authors:  Sophie Bezzenine-Lafollée; Richard Gil; Damien Prim; Jérôme Hannedouche
Journal:  Molecules       Date:  2017-11-04       Impact factor: 4.411

10.  Nucleophilic Aromatic Substitution of Polyfluoroarene to Access Highly Functionalized 10-Phenylphenothiazine Derivatives.

Authors:  Kotaro Kikushima; Haruka Koyama; Kazuki Kodama; Toshifumi Dohi
Journal:  Molecules       Date:  2021-03-04       Impact factor: 4.411
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