Literature DB >> 27434758

Diboron(4) Compounds: From Structural Curiosity to Synthetic Workhorse.

Emily C Neeve1, Stephen J Geier2, Ibraheem A I Mkhalid3, Stephen A Westcott2, Todd B Marder1.   

Abstract

Although known for over 90 years, only in the past two decades has the chemistry of diboron(4) compounds been extensively explored. Many interesting structural features and reaction patterns have emerged, and more importantly, these compounds now feature prominently in both metal-catalyzed and metal-free methodologies for the formation of B-C bonds and other processes.

Entities:  

Year:  2016        PMID: 27434758     DOI: 10.1021/acs.chemrev.6b00193

Source DB:  PubMed          Journal:  Chem Rev        ISSN: 0009-2665            Impact factor:   60.622


  87 in total

1.  Cobalt-Catalyzed 1,1-Diboration of Terminal Alkynes: Scope, Mechanism, and Synthetic Applications.

Authors:  Simon Krautwald; Máté J Bezdek; Paul J Chirik
Journal:  J Am Chem Soc       Date:  2017-03-01       Impact factor: 15.419

2.  Nickel-Catalyzed Stereoselective Arylboration of Unactivated Alkenes.

Authors:  Kaitlyn M Logan; Stephen R Sardini; Sean D White; M Kevin Brown
Journal:  J Am Chem Soc       Date:  2017-12-22       Impact factor: 15.419

3.  Copper-Catalyzed Borylacylation of Activated Alkenes with Acid Chlorides.

Authors:  Yuan Huang; Kevin B Smith; M Kevin Brown
Journal:  Angew Chem Int Ed Engl       Date:  2017-09-18       Impact factor: 15.336

4.  Catalytic Reductions Without External Hydrogen Gas: Broad Scope Hydrogenations with Tetrahydroxydiboron and a Tertiary Amine.

Authors:  Kirill A Korvinson; Hari K Akula; Casina T Malinchak; Dellamol Sebastian; Wei Wei; Tashrique A Khandaker; Magdalena R Andrzejewska; Barbara Zajc; Mahesh K Lakshman
Journal:  Adv Synth Catal       Date:  2019-11-13       Impact factor: 5.837

5.  Ni-Catalyzed Arylboration of Unactivated Alkenes: Scope and Mechanistic Studies.

Authors:  Stephen R Sardini; Alison L Lambright; Grace L Trammel; Humair M Omer; Peng Liu; M Kevin Brown
Journal:  J Am Chem Soc       Date:  2019-06-04       Impact factor: 15.419

6.  Catalytic Enantioselective Arylboration of Alkenylarenes.

Authors:  Kaitlyn M Logan; M Kevin Brown
Journal:  Angew Chem Int Ed Engl       Date:  2016-12-21       Impact factor: 15.336

7.  Catalyst Controlled Regiodivergent Arylboration of Dienes.

Authors:  Stephen R Sardini; M Kevin Brown
Journal:  J Am Chem Soc       Date:  2017-07-12       Impact factor: 15.419

8.  Ketone Synthesis from Benzyldiboronates and Esters: Leveraging α-Boryl Carbanions for Carbon-Carbon Bond Formation.

Authors:  Boran Lee; Paul J Chirik
Journal:  J Am Chem Soc       Date:  2020-01-24       Impact factor: 15.419

9.  Sterically Unprotected Nucleophilic Boron Cluster Reagents.

Authors:  Xin Mu; Jonathan C Axtell; Nicholas A Bernier; Kent O Kirlikovali; Dahee Jung; Alexander Umanzor; Kevin Qian; Xiangyang Chen; Katherine L Bay; Monica Kirollos; Arnold L Rheingold; K N Houk; Alexander M Spokoyny
Journal:  Chem       Date:  2019-08-22       Impact factor: 22.804

10.  Synthesis of Bisheteroarylalkanes by Heteroarylboration: Development and Application of a Pyridylidene-Copper Complex.

Authors:  Yuan Huang; M Kevin Brown
Journal:  Angew Chem Int Ed Engl       Date:  2019-03-27       Impact factor: 15.336

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