Literature DB >> 27415770

Co-Catalyzed Hydroarylation of Unactivated Olefins.

Hiroki Shigehisa1, Takuya Ano1, Hiroshi Honma1, Kousuke Ebisawa1, Kou Hiroya1.   

Abstract

A mild, general, scalable, and functional group tolerant intramolecular hydroarylation of unactivated olefins using a Co(salen) complex, a N-fluoropyridinium salt, and a disiloxane reagent was reported. This method, which was carried out at room temperature, afforded six-membered benzocyclic compounds from mono-, 1,1- or trans-1,2-di, and trisubstituted olefins.

Entities:  

Year:  2016        PMID： 27415770     DOI： 10.1021/acs.orglett.6b01662

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  7 in total

1.  A tethering directing group strategy for ruthenium-catalyzed intramolecular alkene hydroarylation.

Authors:  Praveen Kilaru; Sunil P Acharya; Pinjing Zhao
Journal:  Chem Commun (Camb)       Date:  2018-01-23       Impact factor: 6.222

2.  Mechanistic Interrogation of Co/Ni-Dual Catalyzed Hydroarylation.

Authors:  Sophia L Shevick; Carla Obradors; Ryan A Shenvi
Journal:  J Am Chem Soc       Date:  2018-09-18       Impact factor: 15.419

3.  Cobalt-Catalyzed Hydrogen-Atom Transfer Induces Bicyclizations that Tolerate Electron-Rich and Electron-Deficient Intermediate Alkenes.

Authors:  Darius Vrubliauskas; Christopher D Vanderwal
Journal:  Angew Chem Int Ed Engl       Date:  2020-02-25       Impact factor: 15.336

4.  Cobalt-Catalyzed Cyclization of Unsaturated N-Acyl Sulfonamides: a Diverted Mukaiyama Hydration Reaction.

Authors:  David M Fischer; Moritz Balkenhohl; Erick M Carreira
Journal:  JACS Au       Date:  2022-05-06

5.  Hydroalkylation of Olefins To Form Quaternary Carbons.

Authors:  Samantha A Green; Tucker R Huffman; Ruairí O McCourt; Vincent van der Puyl; Ryan A Shenvi
Journal:  J Am Chem Soc       Date:  2019-05-03       Impact factor: 15.419

6.  Highly chemoselective synthesis of hindered amides via cobalt-catalyzed intermolecular oxidative hydroamidation.

Authors:  Yun-Nian Yin; Rui-Qi Ding; Dong-Chen Ouyang; Qing Zhang; Rong Zhu
Journal:  Nat Commun       Date:  2021-05-05       Impact factor: 14.919

7.  In(OTf)3-catalyzed intramolecular hydroarylation of α-phenylallyl β-ketosulfones - synthesis of sulfonyl 1-benzosuberones and 1-tetralones.

Authors:  Meng-Yang Chang; Kai-Xiang Lai; Yu-Lun Chang
Journal:  RSC Adv       Date:  2020-05-13       Impact factor: 3.361
  7 in total

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